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Along the period, atomic/ionic radius an...

Along the period, atomic/ionic radius and metallic character generally decreases, while IE, EN and nonmetallic character and oxidizing power increases.
  If the ionic radius of `M^(+)` and `X^(-)` are about 135 and 209 pm respectively, then the expected values of atomic radius of M and X may be respectively in pm)
(M and X are metal and non-metal, respectively of same period.) 

A

180,90

B

135,209

C

90, 180

D

Same radius which is average of 135 and 209 pm

Text Solution

AI Generated Solution

The correct Answer is:
To determine the expected atomic radius of the metal (M) and the non-metal (X) based on the given ionic radii of their respective ions (M^+ and X^-), we can follow these steps: ### Step-by-Step Solution: 1. **Understand Ionic Radii**: - The ionic radius of M^+ is given as 135 pm. Cations (positively charged ions) are smaller than their parent atoms because they lose electrons, resulting in a decrease in electron-electron repulsion and a stronger attraction between the remaining electrons and the nucleus. - The ionic radius of X^- is given as 209 pm. Anions (negatively charged ions) are larger than their parent atoms because they gain electrons, which increases electron-electron repulsion and results in a larger size. 2. **Relate Ionic Radius to Atomic Radius**: - For the metal M, since M^+ is smaller than M, we can conclude that the atomic radius of M (r_M) will be greater than 135 pm: \[ r_M > 135 \text{ pm} \] - For the non-metal X, since X^- is larger than X, we can conclude that the atomic radius of X (r_X) will be less than 209 pm: \[ r_X < 209 \text{ pm} \] 3. **Estimate Atomic Radii**: - In general, the atomic radius of metals tends to be larger than their ionic radius by a certain amount. A typical increase might be around 30-50 pm for metals. Therefore, we can estimate: \[ r_M \approx 135 \text{ pm} + 30 \text{ pm} \text{ to } 50 \text{ pm} \implies r_M \approx 165 \text{ pm to } 185 \text{ pm} \] - For non-metals, the atomic radius tends to be smaller than the ionic radius. A typical decrease might also be around 30-50 pm. Therefore, we can estimate: \[ r_X \approx 209 \text{ pm} - 30 \text{ pm} \text{ to } 50 \text{ pm} \implies r_X \approx 159 \text{ pm to } 179 \text{ pm} \] 4. **Conclusion**: - Based on the estimates, the expected atomic radius of M could be around 165-185 pm, and for X, it could be around 159-179 pm. However, since we need to provide specific values, we can summarize: - Expected atomic radius of M: **greater than 135 pm** (let's say around 165 pm) - Expected atomic radius of X: **less than 209 pm** (let's say around 179 pm) ### Final Answer: - The expected values of atomic radius of M and X may be approximately **165 pm** and **179 pm**, respectively.
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