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Statement I: CH3I + OH^(-) to CH3OH + I^...

Statement I: `CH_3I + OH^(-) to CH_3OH + I^(-)` and `CF_3I + OH^(-) to CF_3OH + I^(-)`
Statement II: Both these reactions are nucleophilic substitution reactions. 

A

If both Statement I and Statement II are true and Statement II is the correct explanation of Statement I.

B

If both Statement I and Statement II are true but Statement II is not the correct explanation for Statement I.

C

If Statement I is true but Statement II is false.

D

If Statement I is false but Statement II is true.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we will analyze both statements provided and determine their validity step by step. ### Step 1: Analyze Statement I The first statement discusses two reactions: 1. \( CH_3I + OH^- \rightarrow CH_3OH + I^- \) 2. \( CF_3I + OH^- \rightarrow CF_3OH + I^- \) Both reactions involve a nucleophile (\( OH^- \)) attacking the carbon atom bonded to iodine (I), leading to the substitution of iodine with a hydroxyl group (OH). ### Step 2: Determine the Nature of the Reactions Both reactions are indeed nucleophilic substitution reactions. In these reactions: - \( OH^- \) acts as a nucleophile, attacking the carbon atom. - Iodine (I) is the leaving group. ### Step 3: Compare the Reactivity of the Two Compounds However, we need to consider the structure of the compounds involved: - \( CH_3I \) has a methyl group (which is electron-donating), making it easier for the nucleophile to attack. - \( CF_3I \) has a trifluoromethyl group (which is electron-withdrawing), making the carbon less reactive towards nucleophilic attack. ### Step 4: Conclude on the Rate of Reactions Due to the electron-withdrawing effect of the \( CF_3 \) group, the rate of reaction for \( CF_3I + OH^- \) will be slower compared to \( CH_3I + OH^- \). Therefore, the rates of the two reactions will not be the same. ### Step 5: Analyze Statement II Statement II asserts that both reactions are nucleophilic substitution reactions. This is true, as established in the previous steps. ### Final Conclusion - **Statement I** is **false** because the rates of the two reactions are not the same. - **Statement II** is **true** because both reactions are indeed nucleophilic substitution reactions. Thus, the final answer is that Statement I is false, and Statement II is true. ### Summary of the Solution - Statement I: False (the rates of the reactions are not the same). - Statement II: True (both reactions are nucleophilic substitution reactions).
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