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The general electronic configuration of ...

The general electronic configuration of outer most and penultimate shell is given as `(n-1)s^2(n-1)p^6(n-1)d^x ns^2`. Then for an element with `n = 4` and `x = 7`
The element is isoelectronic with which of the follow ing species? 

A

`Fe^(-)`

B

`N i^(+)`

C

`Cu^(2+)`

D

All of these.

Text Solution

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The correct Answer is:
To solve the problem, we need to determine the electronic configuration of the element based on the provided general electronic configuration and then find which species is isoelectronic with it. ### Step-by-Step Solution: 1. **Identify the given values**: - We have \( n = 4 \) and \( x = 7 \). 2. **Write the general electronic configuration**: - The general electronic configuration is given as: \[ (n-1)s^2(n-1)p^6(n-1)d^x ns^2 \] - Substituting \( n = 4 \) and \( x = 7 \): \[ (4-1)s^2(4-1)p^6(4-1)d^7 4s^2 \] - This simplifies to: \[ 3s^2 3p^6 3d^7 4s^2 \] 3. **Count the total number of electrons**: - From the configuration: - \( 3s^2 \) contributes 2 electrons. - \( 3p^6 \) contributes 6 electrons. - \( 3d^7 \) contributes 7 electrons. - \( 4s^2 \) contributes 2 electrons. - Total electrons: \[ 2 + 6 + 7 + 2 = 17 \text{ electrons} \] 4. **Determine the atomic number**: - The atomic number of the element is equal to the total number of electrons, which is 27. 5. **Identify the element**: - The element with atomic number 27 is Cobalt (Co). 6. **Find isoelectronic species**: - Isoelectronic species have the same number of electrons. - Cobalt (Co) has 27 electrons. - We can look for ions that also have 27 electrons: - **Fe²⁺** (Iron ion): Iron (Fe) has an atomic number of 26, and when it loses 2 electrons, it has 26 electrons. However, Fe³⁺ has 25 electrons. - **Cu²⁺** (Copper ion): Copper (Cu) has an atomic number of 29, and when it loses 2 electrons, it has 27 electrons. - **Mn⁴⁺** (Manganese ion): Manganese (Mn) has an atomic number of 25, and when it loses 4 electrons, it has 21 electrons. - **Fe³⁺** (Iron ion): Iron (Fe) has an atomic number of 26, and when it loses 3 electrons, it has 23 electrons. - The ion that is isoelectronic with Co is **Fe²⁺**. ### Conclusion: The element with \( n = 4 \) and \( x = 7 \) is Cobalt (Co), and it is isoelectronic with **Fe²⁺**.
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