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The equilibrium, P(4(g)) +6Cl(2(g)) Left...

The equilibrium, `P_(4(g)) +6Cl_(2(g)) Leftrightarrow 4PCl_(3(g))` is attained by mixing equal moles of `P_4 and Cl_2` in an evacuated vessel. Then at equilibrium

A

`[Cl_2] gt [PCl_3]`

B

`[Cl_2] gt [P_4]`

C

`[P_4] gt [Cl_2]`

D

`[PCl_3] gt [P_4]`

Text Solution

Verified by Experts

The correct Answer is:
C

`P_(4(g)) +6Cl_(2(g)) Leftrightarrow 4PCl_(3(g))`
One mole of `P_4` reacts with 6 moles of `Cl_2` i.e, at equilibrium `Cl_2` is consumed more than `P_4`. If we start the reaction with equal number of moles of `P_4 and Cl_2` then obviously at equilibrium `[P_(4)] gt [Cl_2]`
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