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Phosphorus pentachloride dissociates as ...

Phosphorus pentachloride dissociates as follows, in a closed reaction vessel, `PCl_(5(g)) Leftrightarrow PCl_(3(g))+Cl_(2(g))`
If total pressure at equilibrium of the reaction mixture is P and degree of dissociation of `PCl_5` is x, the partial pressure of `PCl_3` will be

A

`((x)/(x+1))P`

B

`((2x)/(1-x))P`

C

`((x)/(x-1))P`

D

`((x)/(1-x))P`

Text Solution

Verified by Experts

The correct Answer is:
A

`pcL_(5) Leftrightarrow PCl_3+Cl_2`
`t_(0)" 1 0 0"`
`t_(eq)" 1-x x x"`
`p_(PCl_3)` =Total pressure `xx` Mole fraction of `PCl_3`
`PCl_3=P. ((x)/(1+x))`
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