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The shortest wavelength of the Brackett ...

The shortest wavelength of the Brackett series of a hydrogen-like atom (atomic number of `Z` ) is the same as the shortest wavelength of the Balmer series of hydrogen atom. The value of `z` is

A

2

B

3

C

4

D

6

Text Solution

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The correct Answer is:
To solve the problem, we need to find the atomic number \( Z \) of a hydrogen-like atom such that the shortest wavelength of the Brackett series of this atom is the same as the shortest wavelength of the Balmer series of a hydrogen atom. ### Step-by-Step Solution: 1. **Understanding the Series**: - The **Balmer series** of hydrogen corresponds to transitions from higher energy levels (n = 3, 4, ...) to n = 2. - The **Brackett series** corresponds to transitions from higher energy levels (n = 5, 6, ...) to n = 4. 2. **Finding the Shortest Wavelength of the Balmer Series**: - The shortest wavelength in the Balmer series occurs when the electron transitions from \( n = \infty \) to \( n = 2 \). - The formula for the wavelength is given by: \[ \frac{1}{\lambda_1} = R \left( \frac{1}{2^2} - \frac{1}{\infty^2} \right) = R \left( \frac{1}{4} - 0 \right) = \frac{R}{4} \] - Here, \( R \) is the Rydberg constant. 3. **Finding the Shortest Wavelength of the Brackett Series**: - The shortest wavelength in the Brackett series occurs when the electron transitions from \( n = \infty \) to \( n = 4 \). - The formula for the wavelength is: \[ \frac{1}{\lambda_2} = R Z^2 \left( \frac{1}{4^2} - \frac{1}{\infty^2} \right) = R Z^2 \left( \frac{1}{16} - 0 \right) = \frac{R Z^2}{16} \] 4. **Setting the Wavelengths Equal**: - Since the shortest wavelengths are equal, we set \( \lambda_1 = \lambda_2 \): \[ \frac{R}{4} = \frac{R Z^2}{16} \] 5. **Canceling Rydberg Constant**: - We can cancel \( R \) from both sides (assuming \( R \neq 0 \)): \[ \frac{1}{4} = \frac{Z^2}{16} \] 6. **Cross-Multiplying**: - Cross-multiplying gives: \[ 16 = 4 Z^2 \] 7. **Solving for Z**: - Dividing both sides by 4: \[ Z^2 = 4 \] - Taking the square root: \[ Z = 2 \] ### Conclusion: The value of \( Z \) is \( 2 \).
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