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Hydroboration oxidation and acid hydrati...

Hydroboration oxidation and acid hydration will yield the same product in case of:

A

B

C

`CH_(2) = CH_(2)`

D

`CH_(3)CH= CH-CH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which reaction conditions yield the same product from hydroboration-oxidation and acid hydration, we need to analyze the nature of the alkenes involved. Here's a step-by-step breakdown of the solution: ### Step 1: Understand Acid Hydration - Acid hydration involves the addition of water (H₂O) to an alkene in the presence of an acid (H⁺). - For symmetrical alkenes, this reaction yields a single product (an alcohol) since both sides of the double bond are identical. - For unsymmetrical alkenes, the reaction follows Markovnikov's rule, where the hydroxyl group (OH) attaches to the carbon with the greater number of hydrogen atoms. ### Step 2: Understand Hydroboration-Oxidation - Hydroboration-oxidation involves the addition of borane (BH₃) to the alkene, followed by oxidation with hydrogen peroxide (H₂O₂) in a basic medium. - For symmetrical alkenes, this also yields a single product (an alcohol). - For unsymmetrical alkenes, this reaction follows the anti-Markovnikov rule, where the hydroxyl group attaches to the less substituted carbon. ### Step 3: Identify Symmetrical Alkenes - To ensure that both reactions yield the same product, we need to identify symmetrical alkenes. - Symmetrical alkenes will produce the same alcohol regardless of whether hydroboration-oxidation or acid hydration is used. ### Step 4: Analyze the Given Options - **Option A:** Unsymmetrical alkene (not symmetrical). - **Option B:** Symmetrical alkene (both sides are identical). - **Option C:** Symmetrical alkene (both sides are identical). - **Option D:** Symmetrical alkene (both sides are identical). ### Step 5: Conclusion - The correct answer is that options B, C, and D are symmetrical alkenes, which will yield the same product from both hydroboration-oxidation and acid hydration. ### Final Answer The correct options that yield the same product in both reactions are **B, C, and D**. ---
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