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How many EDTA molecules are required to ...

How many EDTA molecules are required to make an octahedral complex with a `Ca^(2+)` ion?

A

six

B

Three

C

One

D

Two

Text Solution

AI Generated Solution

The correct Answer is:
To determine how many EDTA molecules are required to form an octahedral complex with a \( \text{Ca}^{2+} \) ion, we can follow these steps: ### Step 1: Understand the Structure of EDTA EDTA (ethylenediaminetetraacetic acid) has a specific structure that allows it to bind to metal ions. It contains two nitrogen atoms and four carboxylate groups, which can donate electron pairs to the metal ion. ### Step 2: Identify the Donor Sites Each EDTA molecule has six donor sites: - Two nitrogen atoms - Four oxygen atoms from the carboxylate groups This means that EDTA can form multiple bonds with a metal ion. ### Step 3: Determine the Coordination Number of the Metal Ion In an octahedral complex, the coordination number is typically 6. This means that the metal ion can bond with six ligands or donor atoms. ### Step 4: Relate the Donor Sites to the Coordination Number Since EDTA is a hexa-dentate ligand, it can bind to a metal ion at all six donor sites. Thus, one EDTA molecule can fulfill the requirement for all six coordination sites in the octahedral complex. ### Step 5: Conclusion Therefore, only one EDTA molecule is required to form an octahedral complex with a \( \text{Ca}^{2+} \) ion. ### Final Answer **One EDTA molecule is required.** ---
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