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One mole of a diatomic gas undergoes a t...

One mole of a diatomic gas undergoes a thermodynamic process, whose process equation is `P prop V^(2)`. The molar specific heat of the gas is

A

`(17R)/3`

B

`(17R)/6`

C

`(15R)/4`

D

`(15R)/8`

Text Solution

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The correct Answer is:
To find the molar specific heat of a diatomic gas undergoing a thermodynamic process described by the equation \( P \propto V^2 \), we can follow these steps: ### Step 1: Understand the relationship The given relationship \( P \propto V^2 \) implies that \( P = k V^2 \) for some constant \( k \). This suggests that we can express the relationship in terms of a polytropic process. ### Step 2: Identify the polytropic process In a polytropic process, the relationship can be expressed as: \[ PV^n = \text{constant} \] Comparing this with our equation \( P = k V^2 \), we can rewrite it as: \[ P V^{-2} = k \] This indicates that \( n = -2 \). ### Step 3: Use the formula for molar specific heat The formula for the molar specific heat \( C \) in a polytropic process is given by: \[ C = C_v + \frac{R}{1 - n} \] where \( C_v \) is the molar specific heat at constant volume, and \( R \) is the universal gas constant. ### Step 4: Determine \( C_v \) for a diatomic gas For a diatomic gas, the molar specific heat at constant volume \( C_v \) is: \[ C_v = \frac{5R}{2} \] ### Step 5: Substitute values into the specific heat formula Now substituting \( C_v \) and \( n \) into the specific heat formula: \[ C = \frac{5R}{2} + \frac{R}{1 - (-2)} \] This simplifies to: \[ C = \frac{5R}{2} + \frac{R}{1 + 2} = \frac{5R}{2} + \frac{R}{3} \] ### Step 6: Find a common denominator and combine the terms To combine \( \frac{5R}{2} \) and \( \frac{R}{3} \), we find a common denominator, which is 6: \[ C = \frac{15R}{6} + \frac{2R}{6} = \frac{17R}{6} \] ### Final Answer Thus, the molar specific heat of the gas is: \[ C = \frac{17R}{6} \]
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