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An amount of heat 50J of heat energy is ...

An amount of heat 50J of heat energy is removed from 4 moles of a monatomic ideal gas at constant volume.The temperature drops by

A

`40^(@)C`

B

`30^(@)C`

C

`10^(@)C`

D

`0^(@)C`

Text Solution

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The correct Answer is:
To solve the problem of how much the temperature drops when 50 J of heat energy is removed from 4 moles of a monatomic ideal gas at constant volume, we can follow these steps: ### Step 1: Understand the First Law of Thermodynamics The first law of thermodynamics states: \[ \Delta Q = \Delta U + \Delta W \] Where: - \(\Delta Q\) is the heat added to the system, - \(\Delta U\) is the change in internal energy, - \(\Delta W\) is the work done by the system. Since the process occurs at constant volume, the work done (\(\Delta W\)) is zero: \[ \Delta W = 0 \] Thus, we have: \[ \Delta Q = \Delta U \] ### Step 2: Determine the Change in Internal Energy Given that 50 J of heat is removed from the gas, we can express this as: \[ \Delta Q = -50 \, \text{J} \] Therefore: \[ \Delta U = -50 \, \text{J} \] ### Step 3: Relate Change in Internal Energy to Temperature Change For a monatomic ideal gas, the change in internal energy (\(\Delta U\)) can be expressed as: \[ \Delta U = \frac{3}{2} n R \Delta T \] Where: - \(n\) is the number of moles, - \(R\) is the universal gas constant (\(R \approx 8.314 \, \text{J/(mol K)}\)), - \(\Delta T\) is the change in temperature. ### Step 4: Substitute Known Values We know: - \(n = 4 \, \text{moles}\), - \(\Delta U = -50 \, \text{J}\). Substituting these values into the equation: \[ -50 = \frac{3}{2} \times 4 \times 8.314 \times \Delta T \] ### Step 5: Solve for \(\Delta T\) First, calculate the constant: \[ \frac{3}{2} \times 4 \times 8.314 = 49.884 \, \text{J/K} \] Now, substituting this back into the equation: \[ -50 = 49.884 \Delta T \] To find \(\Delta T\): \[ \Delta T = \frac{-50}{49.884} \approx -1.003 \, \text{K} \] ### Step 6: Convert to Degrees Celsius Since a change of 1 K is equivalent to a change of 1 °C, we can say: \[ \Delta T \approx -1.003 \, \text{°C} \] ### Final Answer The temperature drops by approximately 1 °C.
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