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The increasing order of volatility of hy...

The increasing order of volatility of hydrides of group 16 elements is -

A

`H_(2) O lt H_(2) Te lt H_(2) Se lt H_(2)S`

B

`H_(2)S lt H_(2)O lt H_(2)Se lt H_(2)Te`

C

`H_(2)O lt H_(2) S lt H_(2)Se lt H_(2)Te`

D

`H_(2)Te lt H_(2)Se lt H_(2)S lt H_(2)O`

Text Solution

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The correct Answer is:
To determine the increasing order of volatility of hydrides of group 16 elements, we will analyze the hydrides: H2O (water), H2S (hydrogen sulfide), H2Se (hydrogen selenide), and H2Te (hydrogen telluride). ### Step-by-Step Solution: 1. **Identify the Hydrides**: The hydrides of group 16 elements are H2O, H2S, H2Se, and H2Te. 2. **Understand Volatility**: Volatility refers to how readily a substance vaporizes. Generally, as molecular mass increases, volatility decreases due to stronger intermolecular forces. 3. **Compare Molecular Masses**: - H2O: Molecular mass = 18 g/mol - H2S: Molecular mass = 34 g/mol - H2Se: Molecular mass = 80 g/mol - H2Te: Molecular mass = 130 g/mol 4. **Consider Intermolecular Forces**: - H2O exhibits strong hydrogen bonding, which significantly decreases its volatility. - H2S, H2Se, and H2Te primarily exhibit weaker van der Waals forces, leading to higher volatility compared to H2O. 5. **Order Based on Volatility**: - H2O has the strongest intermolecular forces due to hydrogen bonding, making it the least volatile. - H2S is next, followed by H2Se, and finally H2Te, which has the highest molecular mass but weaker intermolecular forces. 6. **Final Increasing Order of Volatility**: - H2S < H2Se < H2Te < H2O ### Conclusion: The increasing order of volatility of the hydrides of group 16 elements is: **H2S < H2Se < H2Te < H2O**
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