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A redox reaction in which two molecules ...

A redox reaction in which two molecules of an aldehyde reacts to produce a primary alcohol and a carboxylic acid using a hydroxide base is called `:`

A

Cannizzaro reaction

B

Acetylation

C

Decarboxylation

D

None of these

Text Solution

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The correct Answer is:
To solve the question regarding the redox reaction involving aldehydes, we can break down the process step by step. ### Step-by-Step Solution: 1. **Identify the Reactants**: - We start with two molecules of an aldehyde. The general structure of an aldehyde can be represented as RCHO, where R is a hydrocarbon chain. 2. **Understanding the Reaction Conditions**: - The reaction occurs in the presence of a hydroxide base, typically sodium hydroxide (NaOH). The hydroxide ion (OH-) plays a critical role in the reaction. 3. **Nucleophilic Attack**: - The hydroxide ion (OH-) will attack the electrophilic carbon of the aldehyde (C=O). This leads to the formation of an alkoxide intermediate. The double bond between carbon and oxygen will shift, resulting in a negatively charged oxygen. 4. **Formation of Alkoxide**: - After the nucleophilic attack, the intermediate can be represented as R-C(OH)(O-)H. This is an alkoxide ion, which is unstable. 5. **Second Aldehyde Molecule**: - A second molecule of aldehyde (RCHO) will undergo a similar reaction. The hydride ion (H-) from the first aldehyde will now act as a reducing agent and attack the carbon of the second aldehyde. 6. **Formation of Products**: - The reaction will yield two products: - A primary alcohol (R-CH2OH) from the reduction of one aldehyde. - A carboxylic acid (R-COOH) from the oxidation of the other aldehyde. 7. **Identify the Reaction Type**: - This reaction is a redox reaction because one aldehyde is oxidized to a carboxylic acid while the other is reduced to a primary alcohol. 8. **Name of the Reaction**: - This specific reaction is known as the Kenning-Jarvose reaction. ### Final Answer: The redox reaction in which two molecules of an aldehyde react to produce a primary alcohol and a carboxylic acid using a hydroxide base is called the **Kenning-Jarvose reaction**.
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