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When Ethylchloride and alcoholic KOH are...

When Ethylchloride and alcoholic KOH are heated, the compound obtained is

A

`C_(2)H_(4)`

B

`C_(2)H_(2)`

C

`C_(6)H_(6)`

D

`C_(2)H_(6)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the compound obtained when ethyl chloride (C2H5Cl) is heated with alcoholic KOH, we can follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are: - Ethyl chloride (C2H5Cl) - Alcoholic KOH (potassium hydroxide in alcohol) ### Step 2: Understand the Reaction Type Alcoholic KOH is a strong base and promotes elimination reactions (dehydrohalogenation) in alkyl halides. In this case, ethyl chloride will undergo a beta-elimination reaction. ### Step 3: Identify the Structure of Ethyl Chloride Ethyl chloride can be represented as: - CH3-CH2-Cl Here, the carbon atoms are numbered as follows: - The carbon attached to the chlorine (Cl) is the alpha carbon (C1). - The adjacent carbon (C2) is the beta carbon. ### Step 4: Identify the Beta Hydrogen In the ethyl chloride molecule, the beta carbon (C2) has two hydrogen atoms (H). These are the beta hydrogens that can be eliminated during the reaction. ### Step 5: Mechanism of the Reaction 1. The hydroxide ion (OH-) from alcoholic KOH acts as a base and abstracts one of the beta hydrogens from the beta carbon (C2). 2. This leads to the formation of a double bond between the alpha carbon (C1) and beta carbon (C2), while the chlorine atom (Cl) is eliminated as a chloride ion (Cl-). ### Step 6: Write the Reaction The reaction can be summarized as follows: - CH3-CH2-Cl + KOH (alcoholic) → CH2=CH2 + KCl + H2O ### Step 7: Identify the Product The product formed is ethylene (C2H4), which can be represented as: - CH2=CH2 ### Final Answer The compound obtained when ethyl chloride is heated with alcoholic KOH is **C2H4 (ethylene)**. ---
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