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In Uranium (Z=92), the K absorption edge...

In Uranium (Z=92), the K absorption edge is 0.107 Å and the `K_(alpha)` line is 0.126 Å. The wavelength of the L absorption edge is

A

0.7 Å

B

1 Å

C

2 Å

D

3.2 Å

Text Solution

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The correct Answer is:
To find the wavelength of the L absorption edge in Uranium (Z=92), we can follow these steps: ### Step 1: Calculate the energy corresponding to the K absorption edge. The energy of the K absorption edge can be calculated using the formula: \[ E_K = \frac{hc}{\lambda_K} \] where: - \(h\) is Planck's constant (approximately \(4.14 \times 10^{-15} \, \text{eV s}\)), - \(c\) is the speed of light (approximately \(3 \times 10^8 \, \text{m/s}\)), - \(\lambda_K\) is the wavelength of the K absorption edge (given as \(0.107 \, \text{Å}\)). First, we convert the wavelength from Ångströms to meters: \[ 0.107 \, \text{Å} = 0.107 \times 10^{-10} \, \text{m} \] Now, substituting the values: \[ E_K = \frac{(4.14 \times 10^{-15} \, \text{eV s})(3 \times 10^8 \, \text{m/s})}{0.107 \times 10^{-10} \, \text{m}} \approx 115.9 \, \text{keV} \] ### Step 2: Calculate the energy corresponding to the Kα line. Using the same formula for the Kα line: \[ E_{K\alpha} = \frac{hc}{\lambda_{K\alpha}} \] where \(\lambda_{K\alpha} = 0.126 \, \text{Å}\). Converting the wavelength: \[ 0.126 \, \text{Å} = 0.126 \times 10^{-10} \, \text{m} \] Now substituting the values: \[ E_{K\alpha} = \frac{(4.14 \times 10^{-15} \, \text{eV s})(3 \times 10^8 \, \text{m/s})}{0.126 \times 10^{-10} \, \text{m}} \approx 98.4 \, \text{keV} \] ### Step 3: Calculate the energy corresponding to the L absorption edge. Using the relationship: \[ E_{K\alpha} = E_K - E_L \] we can rearrange this to find \(E_L\): \[ E_L = E_K - E_{K\alpha} \] Substituting the values we calculated: \[ E_L = 115.9 \, \text{keV} - 98.4 \, \text{keV} = 17.5 \, \text{keV} \] ### Step 4: Calculate the wavelength of the L absorption edge. Using the energy of the L absorption edge, we can find the wavelength: \[ \lambda_L = \frac{hc}{E_L} \] Substituting the values: \[ \lambda_L = \frac{(4.14 \times 10^{-15} \, \text{eV s})(3 \times 10^8 \, \text{m/s})}{17.5 \times 10^3 \, \text{eV}} \approx 0.709 \, \text{Å} \] ### Final Answer: The wavelength of the L absorption edge is approximately \(0.709 \, \text{Å}\), which can be rounded to \(0.7 \, \text{Å}\). ---
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