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The density of neon will be highest at...

The density of neon will be highest at

A

STP

B

`0^(@)C, 2atm`

C

`273^(@)C,1atm`

D

`0^(@)C, 2 atm`

Text Solution

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The correct Answer is:
To determine the condition at which the density of neon will be highest, we can use the ideal gas law and the relationship between density, pressure, and temperature. ### Step-by-Step Solution: 1. **Understand the Ideal Gas Law**: The ideal gas law is given by the equation: \[ PV = nRT \] where \( P \) is the pressure, \( V \) is the volume, \( n \) is the number of moles, \( R \) is the ideal gas constant, and \( T \) is the temperature in Kelvin. 2. **Relate Moles to Mass**: The number of moles \( n \) can be expressed in terms of mass \( W \) and molar mass \( m \): \[ n = \frac{W}{M} \] where \( M \) is the molar mass of neon. 3. **Express Density**: Density \( D \) is defined as mass per unit volume: \[ D = \frac{W}{V} \] From the ideal gas law, we can rearrange to find \( V \): \[ V = \frac{nRT}{P} \] Substituting the expression for \( n \): \[ V = \frac{WRT}{MP} \] Therefore, substituting \( V \) back into the density equation gives: \[ D = \frac{W}{\frac{WRT}{MP}} = \frac{MP}{RT} \] 4. **Analyze the Density Equation**: From the equation \( D = \frac{MP}{RT} \), we can see that: - Density \( D \) is directly proportional to pressure \( P \). - Density \( D \) is inversely proportional to temperature \( T \). 5. **Determine Conditions for Maximum Density**: To maximize density: - Increase pressure \( P \) (higher pressure leads to higher density). - Decrease temperature \( T \) (lower temperature leads to higher density). 6. **Evaluate Given Options**: - **STP (Standard Temperature and Pressure)**: \( P = 1 \, \text{atm}, T = 273 \, \text{K} \) - **Option 2**: \( 0^\circ C (273 \, \text{K}), P = 2 \, \text{atm} \) - **Option 3**: \( P = 273 \, \text{atm} \) (very high pressure) - **Option 4**: \( 0^\circ C (273 \, \text{K}), P = 2 \, \text{atm} \) (same as option 2) 7. **Select the Highest Density Condition**: Among the options, the condition with the highest pressure and lowest temperature will yield the highest density. The second option (0°C and 2 atm) and the fourth option (0°C and 2 atm) both provide a higher pressure than STP, which will result in a higher density. ### Conclusion: The density of neon will be highest at **0°C and 2 atm**.
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