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Incorrect statement among the following ...

Incorrect statement among the following is :

A

Oxidation state of chromium in chromate and dichomate is same

B

Oxidation of manganese is different in manganate and permanganate

C

Colour of chromate and dichromate is orange

D

Chromate ion gets converted into dichromate ion in acidic medium

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze each statement provided and determine which one is incorrect. ### Step-by-Step Solution: 1. **Statement 1: Oxidation state of chromium in chromate and dichromate is the same.** - **Chromate Ion (CrO4²⁻)**: - Let the oxidation state of Cr be \( x \). - The equation is: \( x + 4(-2) = -2 \) - This simplifies to: \( x - 8 = -2 \) - Therefore, \( x = +6 \). - **Dichromate Ion (Cr2O7²⁻)**: - Let the oxidation state of Cr be \( x \). - The equation is: \( 2x + 7(-2) = -2 \) - This simplifies to: \( 2x - 14 = -2 \) - Therefore, \( 2x = 12 \) and \( x = +6 \). - **Conclusion**: The oxidation state of chromium in both chromate and dichromate is +6. This statement is **true**. 2. **Statement 2: Oxidation state of manganese is different in manganate and permanganate.** - **Manganate Ion (MnO4²⁻)**: - Let the oxidation state of Mn be \( x \). - The equation is: \( x + 4(-2) = -2 \) - This simplifies to: \( x - 8 = -2 \) - Therefore, \( x = +6 \). - **Permanganate Ion (MnO4⁻)**: - Let the oxidation state of Mn be \( x \). - The equation is: \( x + 4(-2) = -1 \) - This simplifies to: \( x - 8 = -1 \) - Therefore, \( x = +7 \). - **Conclusion**: The oxidation state of manganese is +6 in manganate and +7 in permanganate. This statement is **true**. 3. **Statement 3: Color of chromate and dichromate is orange.** - **Chromate Ion**: The color of chromate (CrO4²⁻) is **yellow**. - **Dichromate Ion**: The color of dichromate (Cr2O7²⁻) is **orange**. - **Conclusion**: This statement is **incorrect** because it incorrectly states that both colors are orange. 4. **Statement 4: Chromate ion gets converted to dichromate ion in acidic medium.** - The reaction is: \[ \text{CrO4}^{2-} + 2\text{H}^+ \rightarrow \text{Cr2O7}^{2-} + \text{H2O} \] - **Conclusion**: This statement is **true**. ### Final Answer: The incorrect statement among the options is: **Color of chromate and dichromate is orange.**
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