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The reaction , 2RCHO overset("Al-ethoxid...

The reaction , `2RCHO overset("Al-ethoxide")(rarr) RCOOCH_(2)R` is called -

A

Tischenko reaction

B

Knoevangel reacion

C

Cannizzaro reaction

D

HVZ reaction

Text Solution

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The correct Answer is:
To solve the question regarding the reaction `2RCHO overset("Al-ethoxide")(rarr) RCOOCH_(2)R`, we need to identify the name of the reaction. Let's break down the steps to arrive at the answer. ### Step 1: Identify the Reactants and Products The reaction involves two molecules of an aldehyde (RCHO) reacting in the presence of aluminum ethoxide (Al-ethoxide) to produce an ester (RCOOCH2R). **Hint:** Look at the structure of the reactants and products to understand the transformation occurring in the reaction. ### Step 2: Understand the Mechanism In this reaction, one molecule of the aldehyde is oxidized to a carboxylic acid (RCOOH), while the other molecule is reduced to an alcohol (RCH2OH). These two products then undergo esterification, where water is eliminated to form the ester. **Hint:** Consider how aldehydes can react under specific conditions to form different functional groups. ### Step 3: Identify the Name of the Reaction The reaction described is known as the **Shenko reaction**. This reaction is characterized by the condensation of two aldehydes in the presence of a catalyst (like aluminum ethoxide) to form an ester. **Hint:** Familiarize yourself with various organic reactions and their names to recognize them easily. ### Step 4: Eliminate Other Options - **Novengel Reaction:** Involves aldehydes or ketones with active methylene groups, which is not applicable here. - **Canizaro Reaction:** Involves aldehydes without alpha-hydrogens undergoing self-oxidation and reduction, which does not fit our case since RCHO has alpha-hydrogens. - **HVZ Reaction:** Involves halogenation of carboxylic acids, irrelevant to the formation of esters from aldehydes. **Hint:** Analyzing the characteristics of each reaction can help you eliminate incorrect options. ### Conclusion The reaction `2RCHO overset("Al-ethoxide")(rarr) RCOOCH_(2)R` is called the **Shenko reaction**.
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