Home
Class 12
CHEMISTRY
Reaction of methyl bromide with aqueous ...

Reaction of methyl bromide with aqueous sodium hydroxide involves

A

Racemization

B

`S_(N)1` mechanism

C

Retention of configuration

D

`S_(N)2` mechanism

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of methyl bromide (CH3Br) with aqueous sodium hydroxide (NaOH), we need to analyze the mechanism of the reaction. ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in this reaction are methyl bromide (CH3Br) and sodium hydroxide (NaOH). In aqueous solution, NaOH dissociates into Na⁺ and OH⁻ ions. **Hint**: Always start by identifying the reactants involved in the reaction. 2. **Determine the Type of Alkyl Halide**: Methyl bromide is a primary alkyl halide. In the context of nucleophilic substitution reactions, primary alkyl halides are known to undergo SN2 reactions. **Hint**: Recall the classification of alkyl halides and their reactivity in different substitution mechanisms (SN1 vs. SN2). 3. **Mechanism of Reaction**: In an SN2 reaction, the nucleophile (OH⁻) attacks the carbon atom bonded to the bromine atom from the opposite side (backside attack). This leads to the formation of a transition state where the bond between carbon and bromine is partially broken while the bond between carbon and hydroxide is partially formed. **Hint**: Remember that SN2 reactions involve a backside attack and the formation of a transition state. 4. **Formation of Products**: After the transition state is formed, the bromine atom (Br⁻) is expelled, resulting in the formation of methanol (CH3OH) as the product. The configuration at the carbon atom is inverted due to the backside attack. **Hint**: Focus on the final products and the stereochemical outcome of the reaction. 5. **Conclusion**: The reaction of methyl bromide with aqueous sodium hydroxide proceeds via an SN2 mechanism, resulting in the formation of methanol and the inversion of configuration at the carbon atom. **Hint**: Conclude by summarizing the mechanism and the product formed. ### Final Answer: The reaction of methyl bromide with aqueous sodium hydroxide involves an SN2 mechanism, leading to the formation of methanol (CH3OH) and the inversion of configuration at the carbon atom.
Promotional Banner

Similar Questions

Explore conceptually related problems

Give the mechanism for the reaction of t-butyl bromide with aqueous potassium hydroxide.

Reaction of t-butyl bromide with sodium methoxide produces

Give balance equation for the reaction of aluminium with aqueous sodium hydroxide.

Reaction of C_6H_5CH_2Br with aqueous sodium hydroxide follows........

Write two uses of sodium hydroxide.

Write two uses of sodium hydroxide.

Reactions of C_(6)H_(5)CH_(2)Br with aqueous sodium hydroxide follows……..

Reactions of C_(6)H_(5)CH_(2)Br with aqueous sodium hydroxide follows……..

Reaction of propanamide with ethanolic sodium hydroxide and bromine will give

Assertion. t -Butyl Methyl ether is not prepared by the reaction of t- butyl bromide with sodium methoxide. Reason: Sodium methoxide is a strong nucleophile.