Home
Class 12
CHEMISTRY
CH3MgBr + CO(2)overset("Dry ether")(rarr...

`CH_3MgBr + CO_(2)overset("Dry ether")(rarr)Y overset(H_3O^(o+))(rarr)Z`
Identify Z from the following.

A

Ethyl acetate

B

Acetic acid

C

Propanoic acid

D

Methyl acetate

Text Solution

AI Generated Solution

The correct Answer is:
To identify compound Z in the reaction CH₃MgBr + CO₂ → Y → Z, we can follow these steps: ### Step 1: Understand the Reactants - The reactants are CH₃MgBr (a Grignard reagent) and CO₂ (carbon dioxide). - Grignard reagents are highly reactive organomagnesium compounds that can react with electrophiles. ### Step 2: Reaction of Grignard Reagent with CO₂ - When CH₃MgBr reacts with CO₂ in dry ether, the nucleophilic carbon (C) of the Grignard reagent attacks the electrophilic carbon of CO₂. - This results in the formation of a carboxylate intermediate. ### Step 3: Formation of Intermediate Y - The reaction can be represented as follows: \[ \text{CH}_3\text{MgBr} + \text{CO}_2 \rightarrow \text{CH}_3\text{C(=O)O}^-\text{MgBr}^+ \] - The product Y is a magnesium carboxylate, specifically CH₃C(=O)O⁻MgBr⁺. ### Step 4: Hydrolysis of Intermediate Y - When Y is treated with an acid (H₃O⁺), hydrolysis occurs, converting the carboxylate into a carboxylic acid. - The reaction can be represented as: \[ \text{CH}_3\text{C(=O)O}^-\text{MgBr}^+ + \text{H}_3\text{O}^+ \rightarrow \text{CH}_3\text{C(=O)OH} + \text{MgBr}^+ \] ### Step 5: Identify Compound Z - The product Z formed after hydrolysis is CH₃C(=O)OH, which is acetic acid (or ethanoic acid). ### Final Answer - Therefore, the compound Z is **acetic acid (CH₃COOH)**.
Promotional Banner

Similar Questions

Explore conceptually related problems

(C) overset(H_(3)O^(+)//H_(2)O)(rarr)(E) (D) overset(H_(3)O^(+)//H_(2)O)(rarr) (F) Which of the following statements is // are correct ?

Consider the following sequence of reaction and identify the final product (Z). CH_(3)CH_(2)CH_(2)Br overset("Mg dry ether")rarr (X) overset(CO_(2))rarr (Y) overset(H^(+))rarr(Z)

CH_(3)CONH_(2) overset(H_(3)O^(+))rarr Product is :

Alcohol overset(P + I_2)(rarr)X overset(Mg, dry,"ether")(rarr)Y overset(HCHO)(rarr)Z overset(H_2O //H^+)(rarr)2 - methylpropanol In this sequence of reaction, the starting alcohol is

Give the formulae of [A] and [B] CH_(3)CH_(2)MgBr+CO_(2)overset((i)"Dry ether")underset((ii)H^(+)//H_(2)O)rarr[A]overset(PCl_(5))rarr[B]

Write structures of compounds A,B and C in each of the following reactions: (i) C_(6)H_(5) Br overset("Mg/dry ether")rarr A underset((b)H_(3)O^(+))overset((a) CO_(2)(g))rarr B overset(PCl_(5))rarr C (ii) CH_(3)CN underset((b) H_(3)O^(+))overset((a) SnCl_(2)//HCl)rarr A overset("dil."NaOH)rarr B overset(Delta)rarr C

Identify X in the reaction HCHO + CH_(3)Mgloverset("dry ether")to "Intermediate" overset(H_(2) "O"//H^(+)) to X :

In the reaction CH_(3)CN+2H underset("Ether")overset(HCl)(rarr) X overset("Boiling "H_(2)O)(rarr) Y , the term Y is

In the reaction CH_(3)CN+2H underset("Ether")overset(HCl)(rarr) X overset("Boiling "H_(2)O)(rarr) Y , the term Y is