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For the reaction N(2) + 3 H(2) to 2 NH...

For the reaction
`N_(2) + 3 H_(2) to 2 NH_(3)` The rate of change of concentration for hydrogen is `0.3 xx 10^(-4) Ms^(-1)` The rate of change of concentration of ammonia is :

A

`-0.2 xx 10^(-4) Ms^(-1)`

B

`0.2 xx 10^(-4) Ms^(-1)`

C

`0.1 xx 10^(-4) Ms^(-1)`

D

`0.3 xx 10^(4) Ms^(-1)`

Text Solution

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The correct Answer is:
To find the rate of change of concentration of ammonia (NH₃) for the reaction: \[ N_2 + 3 H_2 \rightarrow 2 NH_3 \] given that the rate of change of concentration of hydrogen (H₂) is \( 0.3 \times 10^{-4} \, \text{Ms}^{-1} \), we can follow these steps: ### Step 1: Identify the stoichiometric coefficients From the balanced chemical equation, we can see the stoichiometric coefficients: - For \( H_2 \), the coefficient is 3. - For \( NH_3 \), the coefficient is 2. ### Step 2: Write the rate expressions The rate of the reaction can be expressed in terms of the change in concentration of the reactants and products. For the reaction, we have: \[ \text{Rate} = -\frac{1}{3} \frac{d[H_2]}{dt} = \frac{1}{2} \frac{d[NH_3]}{dt} \] ### Step 3: Substitute the given rate of change of hydrogen Given that: \[ \frac{d[H_2]}{dt} = -0.3 \times 10^{-4} \, \text{Ms}^{-1} \] we can substitute this into the rate expression: \[ -\frac{1}{3} \left(-0.3 \times 10^{-4}\right) = \frac{1}{2} \frac{d[NH_3]}{dt} \] ### Step 4: Calculate the rate of change of ammonia Now, simplifying the left side: \[ \frac{1}{3} \times 0.3 \times 10^{-4} = \frac{1}{2} \frac{d[NH_3]}{dt} \] Calculating the left side: \[ \frac{0.3}{3} \times 10^{-4} = 0.1 \times 10^{-4} \] So we have: \[ 0.1 \times 10^{-4} = \frac{1}{2} \frac{d[NH_3]}{dt} \] ### Step 5: Solve for \(\frac{d[NH_3]}{dt}\) To find \(\frac{d[NH_3]}{dt}\), we multiply both sides by 2: \[ \frac{d[NH_3]}{dt} = 2 \times 0.1 \times 10^{-4} = 0.2 \times 10^{-4} \, \text{Ms}^{-1} \] ### Final Answer Thus, the rate of change of concentration of ammonia is: \[ \frac{d[NH_3]}{dt} = 0.2 \times 10^{-4} \, \text{Ms}^{-1} \] ---
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