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In the reaction CH(3)COOHoverset(LiAlH...

In the reaction
`CH_(3)COOHoverset(LiAlH_(4))rarr(A)overset(I_(2)+NaOH)rarr(B)overset(Ag("Dust"))rarr(C)`, the final product C is:-

A

`C_2H_5I`

B

`C_2H_5OH`

C

`C_2H_2`

D

`CH_3COCH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given reaction sequence, we will break down each step and identify the products formed at each stage. ### Step 1: Reduction of Acetic Acid The first reaction involves acetic acid (CH₃COOH) reacting with lithium aluminum hydride (LiAlH₄), which is a strong reducing agent. **Reaction:** \[ \text{CH}_3\text{COOH} + \text{LiAlH}_4 \rightarrow \text{CH}_3\text{CH}_2\text{OH} \] **Product A:** The product of this reaction is ethanol (CH₃CH₂OH). ### Step 2: Reaction with Iodine and NaOH Next, ethanol (A) reacts with iodine (I₂) in the presence of sodium hydroxide (NaOH). **Reaction:** 1. Iodine reacts with NaOH to form sodium iodide (NaI) and sodium hypoiodite (NaOI). 2. The NaI acts as an oxidizing agent, oxidizing ethanol to acetaldehyde (CH₃CHO). **Overall Reaction:** \[ \text{CH}_3\text{CH}_2\text{OH} + \text{I}_2 + \text{NaOH} \rightarrow \text{CH}_3\text{CHO} + \text{NaI} + \text{H}_2\text{O} \] **Product B:** The product formed is acetaldehyde (CH₃CHO). ### Step 3: Haloform Reaction The acetaldehyde (B) then undergoes a haloform reaction in the presence of iodine and sodium hydroxide. **Reaction:** \[ \text{CH}_3\text{CHO} + 3\text{I}_2 + 4\text{NaOH} \rightarrow \text{CHI}_3 + \text{HCOONa} + 3\text{NaI} + 3\text{H}_2\text{O} \] **Product B:** The product of this reaction is iodoform (CHI₃). ### Step 4: Reaction with Silver Dust Finally, iodoform (B) reacts with silver dust (Ag). **Reaction:** \[ 2\text{CHI}_3 + 6\text{Ag} \rightarrow \text{C}_2\text{H}_2 + 6\text{AgI} \] **Product C:** The final product formed is acetylene (C₂H₂). ### Final Answer: The final product C is acetylene (C₂H₂). ---
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