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CH(3)Br overset("KCN")(rarr)A underset(L...

`CH_(3)Br overset("KCN")(rarr)A underset(LiAlH_4)overset(4[H])(rarr)CH_(3)CH_(2)NH_(2)`
IUPAC name of A is

A

Methyl cyanide

B

Methyl isonitrile

C

Acetonitrile

D

Ethane nitrile

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to identify the compound A formed from the reaction of CH₃Br with KCN and then determine its IUPAC name. ### Step 1: Identify the reaction between CH₃Br and KCN - The starting compound is CH₃Br (bromomethane). - When CH₃Br reacts with KCN (potassium cyanide), the bromine atom is replaced by the cyanide group (CN⁻). - This reaction is a nucleophilic substitution reaction where the bromine is a leaving group and the cyanide ion acts as the nucleophile. **Reaction:** \[ \text{CH}_3\text{Br} + \text{KCN} \rightarrow \text{CH}_3\text{CN} + \text{KBr} \] ### Step 2: Identify the product A - The product formed from the above reaction is CH₃CN. - CH₃CN is known as acetonitrile or ethane nitrile. ### Step 3: Determine the IUPAC name of A - The IUPAC name for CH₃CN is ethane nitrile. - In IUPAC nomenclature, the longest carbon chain is identified, and the functional group (nitrile in this case) is named accordingly. ### Step 4: Confirm the subsequent reaction with LiAlH₄ - The next part of the question involves the reduction of A (CH₃CN) using LiAlH₄ (lithium aluminium hydride). - LiAlH₄ is a strong reducing agent that can reduce nitriles to primary amines. - The reduction of CH₃CN will yield CH₃CH₂NH₂ (ethylamine). **Reaction:** \[ \text{CH}_3\text{CN} + 4[H] \xrightarrow{\text{LiAlH}_4} \text{CH}_3\text{CH}_2\text{NH}_2 \] ### Final Answer Thus, the IUPAC name of compound A (CH₃CN) is **ethane nitrile**. ---
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