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A gaseous mixture of 2 moles of A, 3 mol...

A gaseous mixture of 2 moles of A, 3 moles of B, 5 moles of C and 10 moles of D is contained in a vessel. Assuming that gases are ideal and the partial pressure of C is 1.5 atm, total pressure is

A

`3 atm`

B

`6 atm`

C

`9 atm`

D

`15 atm`

Text Solution

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The correct Answer is:
To solve the problem, we need to find the total pressure of a gaseous mixture given the partial pressure of one of the gases and the number of moles of each gas in the mixture. Here’s a step-by-step solution: ### Step 1: Identify the number of moles of each gas We are given: - Moles of A (Na) = 2 - Moles of B (Nb) = 3 - Moles of C (Nc) = 5 - Moles of D (Nd) = 10 ### Step 2: Calculate the total number of moles in the mixture The total number of moles (N_total) is the sum of the moles of all gases: \[ N_{total} = N_a + N_b + N_c + N_d \] \[ N_{total} = 2 + 3 + 5 + 10 = 20 \] ### Step 3: Calculate the mole fraction of gas C The mole fraction (X_C) of gas C is calculated using the formula: \[ X_C = \frac{N_C}{N_{total}} \] Substituting the values: \[ X_C = \frac{5}{20} = \frac{1}{4} \] ### Step 4: Use the relationship between partial pressure and mole fraction We know that the partial pressure of a gas in a mixture is given by: \[ P_C = P_t \times X_C \] Where: - \( P_C \) is the partial pressure of gas C (given as 1.5 atm) - \( P_t \) is the total pressure - \( X_C \) is the mole fraction of gas C (calculated as \( \frac{1}{4} \)) ### Step 5: Rearrange the equation to solve for total pressure Rearranging the equation gives: \[ P_t = \frac{P_C}{X_C} \] Substituting the known values: \[ P_t = \frac{1.5 \text{ atm}}{\frac{1}{4}} \] \[ P_t = 1.5 \text{ atm} \times 4 = 6 \text{ atm} \] ### Final Answer The total pressure of the gaseous mixture is **6 atm**. ---
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