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The following reaction occurs in the Bla...

The following reaction occurs in the Blast Furnace where ions ore is reduced to iron metal :
`Fe_(2)O_(3)(s)+3CO(g)hArr 2Fe(l)+3CO_(2)(g)`
Using the Le Chatelier's principle, predict which one of the following will not disturb the equilibrium?

A

Addition of `CO_(2)`

B

Removal of `CO_(2)`

C

Addition of `Fe_(2)O_(3)`

D

Removal of `CO`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem using Le Chatelier's principle, we need to analyze the given equilibrium reaction: \[ \text{Fe}_2\text{O}_3(s) + 3\text{CO}(g) \rightleftharpoons 2\text{Fe}(l) + 3\text{CO}_2(g) \] ### Step-by-Step Solution: 1. **Identify the Components of the Reaction:** - Reactants: Fe₂O₃ (solid) and CO (gas) - Products: Fe (liquid) and CO₂ (gas) 2. **Understand Le Chatelier's Principle:** - Le Chatelier's principle states that if a system at equilibrium is subjected to a change in concentration, temperature, or pressure, the system will adjust to counteract that change and restore a new equilibrium. 3. **Evaluate Each Option:** - **Option 1: Addition of CO₂** - Adding CO₂ increases the concentration of a product. According to Le Chatelier's principle, the equilibrium will shift to the left (backward direction) to reduce the concentration of CO₂, thus disturbing the equilibrium. - **Option 2: Removal of CO₂** - Removing CO₂ decreases the concentration of a product. The equilibrium will shift to the right (forward direction) to produce more CO₂, thus disturbing the equilibrium. - **Option 3: Addition of Fe₂O₃** - Fe₂O₃ is a solid, and the concentration of solids does not affect the equilibrium position. Therefore, adding Fe₂O₃ will not disturb the equilibrium. - **Option 4: Removal of CO** - Removing CO decreases the concentration of a reactant. The equilibrium will shift to the left (backward direction) to produce more CO, thus disturbing the equilibrium. 4. **Conclusion:** - The only action that will not disturb the equilibrium is the addition of Fe₂O₃ (solid). Therefore, the correct answer is **Option 3**.
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