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Regarding the structure of cyanamide ion...

Regarding the structure of cyanamide ion, pick out the wrong statement

A

It has one carbon with a negative charge

B

It has two `sigma` bonds

C

It has two `pi` bonds

D

It has two negatively charged Nitrogen atoms

Text Solution

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The correct Answer is:
To determine the wrong statement regarding the structure of the cyanamide ion, we will analyze the structure and characteristics of the cyanamide ion step by step. ### Step 1: Understand the Structure of Cyanamide Ion Cyanamide ion is derived from cyanamide (NH2CN) by the loss of two hydrogen ions (H+). The structure can be represented as: - **Cyanamide**: H2N-C≡N - **Cyanamide Ion**: After losing 2 H+, the structure becomes: - N≡C-N^(-) (where one nitrogen has a negative charge) ### Step 2: Identify Bonds in the Structure In the cyanamide ion: - There is a triple bond between the carbon and one nitrogen (C≡N). - There is a single bond between the carbon and the other nitrogen (N-C). - The triple bond consists of one sigma bond and two pi bonds. - The single bond consists of one sigma bond. Thus, the bond types in cyanamide ion are: - **Total Sigma Bonds**: 2 (one from C≡N and one from N-C) - **Total Pi Bonds**: 2 (from the triple bond C≡N) ### Step 3: Analyze the Statements Now, let's evaluate the statements provided: 1. **It has one carbon with a negative charge**: This statement is incorrect. The carbon atom in the cyanamide ion does not carry a negative charge; the negative charge is on one of the nitrogen atoms. 2. **It has two sigma bonds**: This statement is correct as we identified two sigma bonds in the structure. 3. **It has two pi bonds**: This statement is also correct since the triple bond consists of two pi bonds. 4. **It has two negatively charged nitrogen atoms**: This statement is incorrect. Only one nitrogen atom carries a negative charge. ### Conclusion The wrong statement regarding the structure of the cyanamide ion is: - **It has one carbon with a negative charge.**
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