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In hydrogen atom, an electron in its gro...

In hydrogen atom, an electron in its ground state absorbs two times of the energy as if requires escaping (13.6 eV) from the atom. The wavelength of the emitted electron will be

A

`1.34xx10^(-10)m`

B

`2.34xx10^(-10)m`

C

`3.34xx10^(-10)m`

D

`4.44xx10^(-10)m`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to follow these steps: ### Step 1: Determine the Ionization Energy The ionization energy (IE) for a hydrogen atom in its ground state (n=1) is given by the formula: \[ \text{IE} = \frac{13.6 \, \text{eV}}{n^2} \] For hydrogen (Z=1) and in the ground state (n=1): \[ \text{IE} = 13.6 \, \text{eV} \] ### Step 2: Calculate the Energy Absorbed by the Electron According to the problem, the electron absorbs twice the ionization energy: \[ \text{Energy absorbed} = 2 \times \text{IE} = 2 \times 13.6 \, \text{eV} = 27.2 \, \text{eV} \] ### Step 3: Calculate the Kinetic Energy of the Emitted Electron The kinetic energy (KE) of the emitted electron after absorbing this energy is given by: \[ \text{KE} = \text{Energy absorbed} - \text{IE} \] Substituting the values: \[ \text{KE} = 27.2 \, \text{eV} - 13.6 \, \text{eV} = 13.6 \, \text{eV} \] ### Step 4: Convert Kinetic Energy to Joules To convert the kinetic energy from electron volts to joules, we use the conversion factor \( 1 \, \text{eV} = 1.6 \times 10^{-19} \, \text{J} \): \[ \text{KE} = 13.6 \, \text{eV} \times 1.6 \times 10^{-19} \, \text{J/eV} \] \[ \text{KE} = 2.176 \times 10^{-18} \, \text{J} \] ### Step 5: Use De Broglie Wavelength Formula The de Broglie wavelength (\( \lambda \)) of the emitted electron can be calculated using the formula: \[ \lambda = \frac{h}{\sqrt{2m \cdot \text{KE}}} \] Where: - \( h = 6.626 \times 10^{-34} \, \text{J s} \) (Planck's constant) - \( m = 9.1 \times 10^{-31} \, \text{kg} \) (mass of electron) ### Step 6: Substitute Values into the Formula Substituting the values into the de Broglie wavelength formula: \[ \lambda = \frac{6.626 \times 10^{-34}}{\sqrt{2 \times 9.1 \times 10^{-31} \times 2.176 \times 10^{-18}}} \] ### Step 7: Calculate the Denominator First, calculate the denominator: \[ 2m \cdot \text{KE} = 2 \times 9.1 \times 10^{-31} \times 2.176 \times 10^{-18} \] \[ = 3.96 \times 10^{-48} \] Now take the square root: \[ \sqrt{3.96 \times 10^{-48}} = 6.293 \times 10^{-24} \] ### Step 8: Calculate the Wavelength Now substitute back into the wavelength formula: \[ \lambda = \frac{6.626 \times 10^{-34}}{6.293 \times 10^{-24}} \] \[ \lambda \approx 1.05 \times 10^{-10} \, \text{m} \] ### Final Answer The wavelength of the emitted electron is approximately: \[ \lambda \approx 3.34 \times 10^{-10} \, \text{m} \]
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