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In a half reaction, nitrate is reduced b...

In a half reaction, nitrate is reduced by `6e^(-)` reduction to x as follows
`7H^(+)+NO_(3)^(-)+6e^(-)rarr 2H_(2)O+x`. The 'x' in the reaction is

A

`NO`

B

`NH_(2)NH_(2)`

C

`NH_(3)`

D

`NH_(2)OH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given half-reaction and determine the value of 'x', we will follow these steps: ### Step 1: Write the half-reaction The half-reaction provided is: \[ 7H^+ + NO_3^- + 6e^- \rightarrow 2H_2O + x \] ### Step 2: Identify the components - On the left side, we have: - 7 protons (H⁺) - 1 nitrate ion (NO₃⁻) - 6 electrons (e⁻) - On the right side, we have: - 2 water molecules (2H₂O) - The unknown 'x' ### Step 3: Analyze the options for 'x' We need to check the possible options for 'x' to see which one balances the equation. #### Option 1: NO - Nitrogen: 1 on both sides (balanced) - Hydrogen: 7 on the left, 4 on the right (unbalanced) - Conclusion: Incorrect. #### Option 2: NH₂NH₂ (Hydrazine) - Nitrogen: 2 on the right (unbalanced) - Conclusion: Incorrect. #### Option 3: NH₃ (Ammonia) - Nitrogen: 1 on both sides (balanced) - Hydrogen: 7 on the left, 4 (from 2H₂O) + 3 (from NH₃) = 7 on the right (balanced) - Oxygen: 3 on the left (from NO₃⁻), 2 (from 2H₂O) on the right (unbalanced) - Conclusion: Incorrect. #### Option 4: NH₂OH (Hydroxylamine) - Nitrogen: 1 on both sides (balanced) - Hydrogen: 7 on the left, 4 (from 2H₂O) + 3 (from NH₂OH) = 7 on the right (balanced) - Oxygen: 3 on the left (from NO₃⁻), 2 (from 2H₂O) + 1 (from NH₂OH) = 3 on the right (balanced) - Conclusion: Correct. ### Step 4: Final Answer The value of 'x' in the half-reaction is: \[ x = NH_2OH \]
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