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In the laboratory, H(2)O(2) is prepared ...

In the laboratory, `H_(2)O_(2)` is prepared by the action of

A

`MnO_(2)` is added to dilute cold `H_(2)SO_(4)`

B

`BaO_(2)` is added to `CO_(2)` bubbling through cold water

C

`PbO_(2)` is added to an acidified solution of `KMnO_(4)`

D

`Na_(2)O_(2)` is added to boiling water

Text Solution

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The correct Answer is:
To solve the question regarding the laboratory preparation of hydrogen peroxide (H₂O₂), we will analyze the options provided and identify the correct method of preparation. ### Step-by-Step Solution: 1. **Understanding the Options**: We have four options to consider for the preparation of H₂O₂ in the laboratory: - Option A: MnO₂ is added to dilute cold H₂SO₄. - Option B: BaO₂ is added to CO₂ bubbling through cold water. - Option C: PbO₂ is added to an acidified solution of KMnO₄. - Option D: NaO₂ is added to boiling water. 2. **Analyzing Option A**: - MnO₂ (manganese dioxide) does not react with dilute cold H₂SO₄ to produce H₂O₂. This option is incorrect. 3. **Analyzing Option B**: - Barium peroxide (BaO₂) can react with carbon dioxide (CO₂) when bubbled through cold water. The reaction produces barium carbonate (BaCO₃) and hydrogen peroxide (H₂O₂). This method is valid for the preparation of H₂O₂. Therefore, this option is correct. 4. **Analyzing Option C**: - Lead dioxide (PbO₂) does not react with an acidified solution of potassium permanganate (KMnO₄) to produce H₂O₂. This option is incorrect. 5. **Analyzing Option D**: - Sodium peroxide (NaO₂) does not produce H₂O₂ when added to boiling water. This option is incorrect. 6. **Conclusion**: - The only correct method for the laboratory preparation of hydrogen peroxide from the given options is **Option B**: BaO₂ is added to CO₂ bubbling through cold water. ### Final Answer: **BaO₂ is added to CO₂ bubbling through cold water.**
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