Home
Class 12
CHEMISTRY
Xenon trioxide (XeO(3)) forms xenate ion...

Xenon trioxide `(XeO_(3))` forms xenate ion in alkaline medium.
`XeO_(3)+NaOH rarr Na[HXeO_(4)]`
But the xenate ions slowly disproportionate in alkaline solution as `Na[HXeO_(4)]+NaOH rarr Z+Xe+O_(2)+H_(2)O`
The compound Z is expexted to be

A

`Na_(2)XeO_(3)`

B

`Na_(2)XeO_(4)`

C

`Na_(4)XeO_(6)`

D

`Na_(4)XeO_(4)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the reactions involving xenon trioxide (XeO₃) and its interaction with sodium hydroxide (NaOH) in an alkaline medium. ### Step-by-Step Solution: 1. **Identify the Initial Reaction**: - Xenon trioxide reacts with sodium hydroxide to form the xenate ion. - The reaction can be written as: \[ \text{XeO}_3 + \text{NaOH} \rightarrow \text{Na[HXeO}_4] \] 2. **Disproportionation Reaction**: - The xenate ion (Na[HXeO₄]) undergoes disproportionation in the alkaline solution. - The reaction can be represented as: \[ \text{Na[HXeO}_4] + \text{NaOH} \rightarrow Z + \text{Xe} + \text{O}_2 + \text{H}_2\text{O} \] 3. **Determine the Product Z**: - We need to identify the compound Z formed in the reaction. - The xenate ion (Na[HXeO₄]) has a xenon oxidation state of +6. Upon disproportionation, xenon is released as elemental Xe (oxidation state 0), and oxygen is released as O₂. - The remaining product Z must have xenon in a lower oxidation state. 4. **Balancing the Reaction**: - The balanced equation for the disproportionation reaction is: \[ 2 \text{Na[HXeO}_4] + 2 \text{NaOH} \rightarrow \text{Na}_4\text{XeO}_6 + \text{Xe} + \text{O}_2 + 2 \text{H}_2\text{O} \] - Here, we have 4 sodium (Na) on the product side, indicating that Z must be Na₄XeO₆. 5. **Conclusion**: - The compound Z is expected to be Na₄XeO₆. ### Final Answer: The compound Z is **Na₄XeO₆**. ---
Promotional Banner

Similar Questions

Explore conceptually related problems

The xenate ion (HXeO_(4)^(-)) undergoes disproportionation reaction to produce perxenate ion XeO_(5)^(4-) 2HXeO_(4)^(-)+2OH^(-)toXeO_(6)^(4-)+Xe+O_(2)+2H_(2)O The shape of xenate ion and perxenate ions is respectively:

In the given reaction: P_4 + NaOH + H_2O rarr PH_3 + NaH_2PO_2

Assertion (A): Sodium perxenate (Na_(4)XeO_(6)) reacts with NaF in acidic medium to give XeO_(3) and F_(2) Reason (R ): XeO_(6)^(4-) is a stronger oxidant than F_(2) .

In the reactions HCl + NaOH rightarrow NaCl + H_(2)O + x cal. H_(2)SO_(4) + 2NaOH rightarrow Na_(2)SO_(4) + 2 H_(2)O + y cal.

Calculate number of moles of Na2so4 produced from 1 mole of NaOH 2NaOH + H_(2)SO_(4) to NaSO_(4)+ 2H_(2)O

AgCl dissolved in excess of NH_(3), KCN and Na_(2)S_(2)O_(3) solutions the complex produces ions

Complete the following chemical equation : (i) P_(4)+NaOH+H_(2)Orarr (ii) XeF_(4)+O_(2)F_(2)rarr

Complete the following chemical equations : P_4(s) + NaOH(aq) + H_2O rarr (ii) Ca_3P_2(s) + H_2O(l) rarr

What is the n-factor for H_(3)PO_(4) in the reaction 2NaOH+H_(3)PO_(4)rarr Na_(2)HPO_(4)+2H_(2)O ?

In alkaline medium , KMnO_(4) reacts as follows 2KMnO_(4)+2KOH rarr 2K_(2)MnO_(4)+H_(2)O+O Therefore, the equivalent mass of KMnO_(4) will be