Which of the following compounds is used in anti - knock compositions to prevent the deposition of oxides of lead on spark plug, combustion chamber and exhaust pipe?
Which of the following compounds is used in anti - knock compositions to prevent the deposition of oxides of lead on spark plug, combustion chamber and exhaust pipe?
A
Benzene
B
Glycol
C
1, 2-Dibromoethane
D
Glycerol
Text Solution
AI Generated Solution
The correct Answer is:
To solve the question, we need to identify which compound is used in anti-knock compositions to prevent the deposition of lead oxides in engines. Here’s a step-by-step breakdown of the solution:
### Step 1: Understand the Context
Anti-knock agents are additives used in fuels to prevent knocking during combustion. Knocking can cause engine damage and is often associated with the presence of lead in gasoline.
**Hint:** Look for compounds that are known to be used in fuel additives or anti-knock formulations.
### Step 2: Identify the Compounds
The question provides several options (not listed here). We need to focus on the compounds that are commonly known to be used in anti-knock formulations.
**Hint:** Recall common anti-knock agents used historically in gasoline.
### Step 3: Research Common Anti-Knock Agents
Historically, tetraethyl lead was used as an anti-knock agent, but it led to the deposition of lead oxides in engine components. To mitigate this, other compounds were introduced.
**Hint:** Consider alternatives to lead-based compounds that prevent lead oxide deposition.
### Step 4: Identify 1,2-Dibromoethane
1,2-Dibromoethane is known to be used in anti-knock compositions. It helps to prevent the deposition of lead oxides on engine parts like spark plugs and combustion chambers.
**Hint:** Look for information on 1,2-Dibromoethane and its applications in automotive fuel.
### Step 5: Confirm the Answer
Based on the information gathered, we can conclude that 1,2-Dibromoethane is indeed the compound used to prevent the deposition of lead oxides in the engine.
**Final Answer:** The compound used in anti-knock compositions to prevent the deposition of oxides of lead is **1,2-Dibromoethane** (option number 3).
### Summary of Steps:
1. Understand the role of anti-knock agents.
2. Identify the compounds listed in the options.
3. Research common anti-knock agents.
4. Identify the specific role of 1,2-Dibromoethane.
5. Confirm that 1,2-Dibromoethane is the correct answer.
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This law was given by, a French chemist , Joseph Proust. He stated that a given compound always contains exactly the same proportion of elements by weight. Proust worked with two samples of curpic carbonate- one of which was of natural origin and the other was synthetic one . He found that the composition of elements present in it was for both the samples as shown below: Thus, irrespective of the source, a given compound always contains same elements in the same proportion. The validity of this law has been confrmed by various experiments. It is sometimes also reffered to as Law of constant composition. Limitation: This law is not applicable if the compound is formed from different isotopes of an element . The two isotopes of carbon C-12 and C-14 form carbondioxide C^(12)O_(2) and C^(14)O_(2) . The ratio of C : O is 12 : 32 and 14 : 32 respectively .It is not a constant ratio. 6.488 g lead with 1.002 g oxygen to form an oxide. This oxide is also obtained by heating Pb(NO_(3))_(2) , It is found that % of lead in this oxide is 86.62 .Show that these date illustrate the law of definite proportions.
Consider the following statements regarding compounds which cause global warming X is a hydrocarbon, A and B are neutral oxides of nitrogen, C is a blue coloured gas and D is released when H_(2)S is reacted with oxygen. Identify the correct statements about X, A , B, C and D. (I) X is mainly present in natural gas (II) In A and B one is diamagnetic and another one is paramagnetic (III) C can be identified by using liquid element in d-block (IV) D causes acid rain
When an atom or an ion is missing from its normal lattice site, a lattice vacancy (Schottky defect) is created. In stoichimetric ionic crystals, a vacancy of one ion has to be accompanied by the vacancy of the oppositely charged ion in order to maintain electrical neutrality. In a Frenkel defect an ion leaves its position in the lattice and occupies an interstitial void. This is the Frenkel defect commonly found along with the Schottky defects and interstitials. In pure alkali halides, Frenkel defects are not found since the ions cannot get into the interstitial sites. Frenkel defects are found in silver halides because of the small size of the Ag^(+) ion. Unlike Schottky defects, Frenkel defects do not change the denstiy of the solids. In certain ionic solids (e.q. AgBr) both Schottky and Frenkel defects occur. The defects discussed above do not disturb the stoichiometry of the crystalline material. There is large variety of non-stoichiomertic inorganic solids which contain an excess or deficiency of one of the elements. Such solids showing deviations from the ideal stoichiometric composition from an inmportant group of solids. For example in the vanadium oxide, VO_(x) , x can be anywhere between 0.6 and 1.3. There are solids which are difficult to prepare in the stoichiometric composition. Thus, the ideal composition in compounds such as FeO is difficult to obtain (normally we get a composition of Fe_(0.95)O but it may range from Fe_(0.93)O " to " Fe_(0.96)O ). Non-stoichiometric behaviour is most commonly found for transition metal compounds though is also known for some lanthanoids and actinoids. Zinc oxide loses oxygen reversibly at high temperature and turns yellow in colour. The excess metal is accommodated interstitially, giving rise to electrons trapped in the neighbourhood. The enhanced electrical conductivity of the non-stoichiometric ZnO arises from these electrons.ltrbgt Anion vacancies in alkali halides are produced by heating the alkali halide crystals in an atmosphere of the alkali metal vapur. When the metal atoms deposit on the surface they diffuse into the crystal and after ionisation the alkali metal ion occupies cationic vacancy whereas electron occupies anionic vacancy. Electrons trapped in anion vacancies are referred to as F-centers (from Farbe the German word for colour) that given rise to interesting colour in alkali halides. Thus, the excess of potassium in KCl makes the crytal appear violet and the excess of lithium in LiCl makes it pink. When LiCl is heated into the vapour of lithium, the crystal acquires pink colour. This is due to
When an atom or an ion is missing from its normal lattice site, a lattice vacancy (Schottky defect) is created. In stoichimetric ionic crystals, a vacancy of one ion has to be accompanied by the vacancy of the oppositely charged ion in order to maintain electrical neutrality. In a Frenkel defect an ion leaves its position in the lattice and occupies an interstitial void. This is the Frenkel defect commonly found along with the Schottky defects and interstitials. In pure alkali halides, Frenkel defects are not found since the ions cannot get into the interstitial sites. Frenkel defects are found in silver halides because of the small size of the Ag^(+) ion. Unlike Schottky defects, Frenkel defects do not change the denstiy of the solids. In certain ionic solids (e.q. AgBr) both Schottky and Frenkel defects occur. The defects discussed above do not disturb the stoichiometry of the crystalline material. There is large variety of non-stoichiomertic inorganic solids which contain an excess or deficiency of one of the elements. Such solids showing deviations from the ideal stoichiometric composition from an inmportant group of solids. For example in the vanadium oxide, VO_(x) , x can be anywhere between 0.6 and 1.3. There are solids which are difficult to prepare in the stoichiometric composition. Thus, the ideal composition in compounds such as FeO is difficult to obtain (normally we get a composition of Fe_(0.95)O but it may range from Fe_(0.93)O " to " Fe_(0.96)O ). Non-stoichiometric behaviour is most commonly found for transition metal compounds though is also known for some lanthanoids and actinoids. Zinc oxide loses oxygen reversibly at high temperature and turns yellow in colour. The excess metal is accommodated interstitially, giving rise to electrons trapped in the neighbourhood. The enhanced electrical conductivity of the non-stoichiometric ZnO arises from these electrons.ltrbgt Anion vacancies in alkali halides are produced by heating the alkali halide crystals in an atmosphere of the alkali metal vapur. When the metal atoms deposit on the surface they diffuse into the crystal and after ionisation the alkali metal ion occupies cationic vacancy whereas electron occupies anionic vacancy. Electrons trapped in anion vacancies are referred to as F-centers (from Farbe the German word for colour) that given rise to interesting colour in alkali halides. Thus, the excess of potassium in KCl makes the crytal appear violet and the excess of lithium in LiCl makes it pink. Stongly heated ZnO crystal can conduct electricity. This is due to
When an atom or an ion is missing from its normal lattice site, a lattice vacancy (Schottky detect) is created In stoichiometric ionic crystals, a vacancy of one ion has to be accompanied by the vacancy of the oppositely charged ion in order to maintain electrical neutrality. In a Frenkel defect an ion leaves its position in the lattice and occupies an interstitial void.This is the Frenkel defect commonly found along with the Schottky defects and interstitials.In pure alkali halides, Frendel defect are not found since the ions cannot get into the intenstitial sites.Frenkel defects are found in silver halides because of the small size of the Ag^+ ion.Unlike Schottky defects. Frenkel defects do not change the density of the solids.In certain ionic solids (e.g. AgBr) both Schottky and Frenkel defects occur. The defects discussed above do not disturb the stoichiometry of the crystalline meterial.There is large Such solids showing deviations from the ideal stoichiometric composition form an important group of solids For example in the vanadium oxide, VO_x , x can be anywhere between 0.6 and 1.3.There are solids which are difficult to prepare in the stoichiometric composition.Thus, the ideal composition in compounds such as FeO is difficult to obtain (normally we get a composition of Fe_(0.85) O but it may range from Fe_(0.93) O to Fe_(0.96)O ).Non-stoichiometric behaviour is most commonly found for transition metal compounds through is also known for some lanthanoids and actinodes. Zinc oxide loses oxygen reversibly at high temperature and turns yellow in colour.The excess metal is accomdated interstitially, giving rise to electrons trapped in the neighbourhood.the enhanced electrical conductivity of the non-stoichiometric ZnO arises from these electrons . Anion vacancies in alkali halides are produced by heating the alkali halide crystals in an atmosphere of the alkali metal vapour.When the metal atoms deposite on the surface they diffuse into the crystal and after ionisation the alkali metal ion occupies cationic vacancy whereas electron occupies anionic vacancy.Electrons trapped in anion vacancies are referred to as F-centres (from Farbe the German word for colour) that gives rise to interesting colour in alkali halides.Thus, the excess of potassium in KCl makes the crystal appear violet and the excess of lithium in LiCl makes it pink. In the crystal of Fe_(0.93)O , the percentage of Fe (II) will be
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