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The ppi-ppi bond is present in...

The `ppi-ppi` bond is present in

A

`XeO_(3)`

B

`SO_(4)^(2-)`

C

`SO_(2)`

D

All of these

Text Solution

AI Generated Solution

The correct Answer is:
To determine where the p-pi-p-pi bond is present, we need to analyze the given options step by step. ### Step 1: Understanding p-pi-p-pi Bonds A p-pi-p-pi bond is formed by the overlap of p orbitals from two different atoms. This bond is typically found in compounds where there are multiple bonds (double or triple bonds) involving p orbitals. ### Step 2: Analyzing the First Option - XeO3 - **Xenon (Xe)** has the electronic configuration of [Kr] 4d10 5s2 5p6. - In XeO3, xenon forms double bonds with three oxygen atoms. - The bond between xenon and oxygen involves the overlap of xenon's 5p orbitals with oxygen's 2p orbitals. - Therefore, the bonds in XeO3 are indeed p-pi-p-pi bonds. ### Step 3: Analyzing the Second Option - SO4^2- - **Sulfur (S)** has the electronic configuration of [Ne] 3s2 3p4. - In SO4^2-, sulfur forms double bonds with two oxygen atoms and single bonds with two other oxygen atoms. - The double bonds involve the overlap of sulfur's 3p orbitals with oxygen's 2p orbitals. - Thus, SO4^2- also contains p-pi-p-pi bonds. ### Step 4: Analyzing the Third Option - SO2 - In SO2, sulfur again has the electronic configuration of [Ne] 3s2 3p4. - Sulfur forms a double bond with one oxygen atom and a single bond with another. - The double bond involves the overlap of sulfur's 3p orbitals with oxygen's 2p orbitals. - Therefore, SO2 also contains p-pi-p-pi bonds. ### Conclusion All three compounds (XeO3, SO4^2-, and SO2) contain p-pi-p-pi bonds due to the overlap of p orbitals between sulfur or xenon and oxygen. ### Final Answer The p-pi-p-pi bond is present in all of the above compounds: **XeO3, SO4^2-, and SO2**. ---
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