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The Earth's atmosphere consists primaril...

The Earth's atmosphere consists primarily of oxygen `(21%)` and nitrogen `(78%)`. The rms speed of oxygen molecules `(O_(2))` in the atmosphere at a certain location is 535 m/s. The rms speed of the nitrogen molecules at this location will be [Given `"1 amu "=1.66xx10^(-26)" kg, molecular mass of "O_(2)=32," molecular mass of "N_(2)=28]`

A

572 m/s

B

437 m/s

C

835 m/s

D

715 m/s

Text Solution

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The correct Answer is:
To find the root mean square (rms) speed of nitrogen molecules in the atmosphere, we can use the formula for rms speed: \[ v_{\text{rms}} = \sqrt{\frac{3RT}{M}} \] where: - \( R \) is the universal gas constant, \( R = 8.314 \, \text{J/(mol K)} \) - \( T \) is the temperature in Kelvin - \( M \) is the molar mass in kg/mol ### Step 1: Calculate the Temperature (T) We know the rms speed of oxygen \( (O_2) \) is given as 535 m/s. We can use this information to find the temperature \( T \). Using the rms speed formula for oxygen: \[ v_{\text{rms, O2}} = \sqrt{\frac{3RT}{M_{O2}}} \] Substituting the known values: \[ 535 = \sqrt{\frac{3 \times 8.314 \times T}{32 \times 10^{-3}}} \] ### Step 2: Square Both Sides To eliminate the square root, we square both sides: \[ 535^2 = \frac{3 \times 8.314 \times T}{32 \times 10^{-3}} \] Calculating \( 535^2 \): \[ 287225 = \frac{3 \times 8.314 \times T}{0.032} \] ### Step 3: Rearranging the Equation Now, rearranging the equation to solve for \( T \): \[ T = \frac{287225 \times 0.032}{3 \times 8.314} \] ### Step 4: Calculate the Temperature (T) Calculating \( T \): \[ T = \frac{9171.2}{24.942} \approx 367.21 \, \text{K} \] ### Step 5: Calculate the rms Speed of Nitrogen (N2) Now we will use the temperature \( T \) to find the rms speed of nitrogen \( (N_2) \): \[ v_{\text{rms, N2}} = \sqrt{\frac{3RT}{M_{N2}}} \] Substituting the values: \[ v_{\text{rms, N2}} = \sqrt{\frac{3 \times 8.314 \times 367.21}{28 \times 10^{-3}}} \] ### Step 6: Calculate the rms Speed of Nitrogen (N2) Calculating \( v_{\text{rms, N2}} \): \[ v_{\text{rms, N2}} = \sqrt{\frac{3 \times 8.314 \times 367.21}{0.028}} \] Calculating the numerator: \[ 3 \times 8.314 \times 367.21 \approx 9171.2 \] Now substituting back: \[ v_{\text{rms, N2}} = \sqrt{\frac{9171.2}{0.028}} \approx \sqrt{327,000} \approx 571.93 \, \text{m/s} \] ### Step 7: Round the Answer Rounding to a reasonable figure, we get: \[ v_{\text{rms, N2}} \approx 572 \, \text{m/s} \] ### Final Answer The rms speed of nitrogen molecules at this location is approximately **572 m/s**. ---
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