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(CH(3))(3) CMgCl on reaction with D(2)O ...

`(CH_(3))_(3) CMgCl` on reaction with `D_(2)O` produces

A

`(CH_(3))_(3)CD`

B

`(CH_(3))_(3)OD`

C

`(CD_(3))_(3)CD`

D

`(CD_(3))_(3)OD`

Text Solution

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The correct Answer is:
To determine the product of the reaction between (CH₃)₃CMgCl (a Grignard reagent) and D₂O (heavy water), we can follow these steps: ### Step 1: Identify the Reactants The reactants are: - (CH₃)₃CMgCl (a Grignard reagent) - D₂O (heavy water) ### Step 2: Understand the Nature of Grignard Reagents Grignard reagents are highly reactive organomagnesium compounds. In (CH₃)₃CMgCl, the carbon atom (C) bonded to magnesium (Mg) has a partial negative charge due to the electronegativity difference between carbon and magnesium. Thus, we can represent it as: - C δ- (carbon with a partial negative charge) - Mg δ+ (magnesium with a partial positive charge) ### Step 3: Ionization of D₂O D₂O can ionize to produce: - D⁺ (deuterium ion) - OD⁻ (deuteroxide ion) ### Step 4: Reaction Mechanism In the reaction, the carbon atom (C) of the Grignard reagent will attack the D⁺ ion from D₂O, while the magnesium ion (Mg) will bond with the OD⁻ ion. ### Step 5: Write the Products The products of the reaction will be: - The carbon will bond with D, forming (CH₃)₃C-D. - The magnesium will bond with the deuteroxide ion, forming Mg(OD)Cl. Thus, the overall product can be represented as: - (CH₃)₃C-D + Mg(OD)Cl ### Final Product The main product of the reaction is: - (CH₃)₃C-D (tert-butyl deuteride) - Mg(OD)Cl (magnesium deuteroxide chloride) ### Summary of the Reaction The reaction of (CH₃)₃CMgCl with D₂O produces: - (CH₃)₃C-D (tert-butyl deuteride) - Mg(OD)Cl ---
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