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Which of the following will produce only...

Which of the following will produce only one product on reduction with `LiAlH_(4)` ?

A

`CH_(3)COOCH_(2)CH_(3)`

B

`CH_(3)CH_(2)OCOCH_(2)CH_(3)`

C

`CH_(3)CH_(2)CH_(2)OCOCH_(3)`

D

`CH_(3)CH_(2)OCOCH_(2)CH_(2)CH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question of which compound will produce only one product upon reduction with LiAlH4, we will analyze each compound provided in the options. ### Step-by-Step Solution: 1. **Identify the Compounds**: - The first compound is CH3C(=O)OCH2CH3 (ethyl acetate). - The second compound is CH3CH2OC(=O)OCH2CH3. - The third compound is CH3CH2CH2O2C(=O)OCH3. - The fourth compound is CH3CH2O2C(=O)OCH2CH3. 2. **Understanding LiAlH4 as a Reducing Agent**: - LiAlH4 (Lithium Aluminum Hydride) is a strong reducing agent that can reduce esters, aldehydes, and ketones to alcohols. 3. **Analyzing Each Compound**: - **First Compound (Ethyl Acetate)**: - Upon reduction, it will yield ethanol (CH3CH2OH) as the only product. - **Second Compound**: - This compound will likely yield two different products upon reduction due to the presence of both an ether and an ester functional group. - **Third Compound**: - This compound will also yield multiple products upon reduction, as it has both an ether and an ester that can be reduced. - **Fourth Compound**: - Similar to the second and third compounds, this will yield multiple products due to the presence of both an ether and an ester. 4. **Conclusion**: - The only compound that produces a single product upon reduction with LiAlH4 is the first compound, ethyl acetate (CH3C(=O)OCH2CH3), which reduces to ethanol (CH3CH2OH). ### Final Answer: The correct answer is the first compound: **CH3C(=O)OCH2CH3 (ethyl acetate)**. ---
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