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Total number of elements which are prese...

Total number of elements which are present in a row on the periodic table between those elements, whose wavelength of `K_(alpha)` lines are equal to 250 and 179 pm are ( Rydberg constant = `1.097xx10^7m^-1` )

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To solve the problem, we need to find the total number of elements present in a row on the periodic table between the elements whose K_alpha wavelengths are equal to 250 pm and 179 pm. We will use Moseley's law to relate the wavelengths to the atomic numbers. ### Step-by-step Solution: 1. **Understanding Moseley's Law**: Moseley's law states that the square root of the frequency (f) of the emitted X-rays is proportional to the atomic number (Z) of the element: \[ f = a(Z - b) \] where \( a \) and \( b \) are constants. 2. **Relating Wavelength to Frequency**: The frequency \( f \) is related to the wavelength \( \lambda \) by the equation: \[ f = \frac{1}{\lambda} \] Therefore, we can rewrite Moseley's law in terms of wavelength: \[ \frac{1}{\lambda} = a(Z - b) \] 3. **Using the Rydberg Constant**: Given that the Rydberg constant \( a = 1.097 \times 10^7 \, \text{m}^{-1} \), we can substitute this value into our equation. 4. **Calculating for \( \lambda = 250 \, \text{pm} \)**: Convert \( \lambda \) into meters: \[ \lambda = 250 \, \text{pm} = 250 \times 10^{-12} \, \text{m} \] Now, substitute into the equation: \[ \frac{1}{250 \times 10^{-12}} = 1.097 \times 10^7 (Z - 1) \] Solving for \( Z \): \[ 4 \times 10^{6} = 1.097 \times 10^7 (Z - 1) \] \[ Z - 1 = \frac{4 \times 10^{6}}{1.097 \times 10^7} \] \[ Z - 1 \approx 0.364 \implies Z \approx 23 \] 5. **Calculating for \( \lambda = 179 \, \text{pm} \)**: Convert \( \lambda \) into meters: \[ \lambda = 179 \, \text{pm} = 179 \times 10^{-12} \, \text{m} \] Substitute into the equation: \[ \frac{1}{179 \times 10^{-12}} = 1.097 \times 10^7 (Z - 1) \] Solving for \( Z \): \[ 5.58 \times 10^{6} = 1.097 \times 10^7 (Z - 1) \] \[ Z - 1 = \frac{5.58 \times 10^{6}}{1.097 \times 10^7} \] \[ Z - 1 \approx 0.508 \implies Z \approx 27 \] 6. **Finding the Total Number of Elements**: The atomic numbers corresponding to the wavelengths are \( Z = 23 \) and \( Z = 27 \). The elements between these atomic numbers are: - 24 (Chromium) - 25 (Manganese) - 26 (Iron) Therefore, the total number of elements between atomic numbers 23 and 27 is: \[ 27 - 23 - 1 = 3 \] ### Final Answer: The total number of elements present in a row on the periodic table between those elements is **3**.
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