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2N2O5(g)rarr4NO2(g)+O2(g) what is the ra...

`2N_2O_5(g)rarr4NO_2(g)+O_2(g)` what is the ratio of the rate of decomposition of `N_2O_5` to rate of formation of `O_2` ?

A

`1:2`

B

`2:1`

C

`1:4`

D

`4:1`

Text Solution

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The correct Answer is:
To find the ratio of the rate of decomposition of \( N_2O_5 \) to the rate of formation of \( O_2 \) in the reaction: \[ 2N_2O_5(g) \rightarrow 4NO_2(g) + O_2(g) \] we can follow these steps: ### Step 1: Write the Rate Expressions For the given reaction, we can express the rates of change of concentrations as follows: - The rate of decomposition of \( N_2O_5 \) is given by: \[ \text{Rate of decomposition of } N_2O_5 = -\frac{1}{2} \frac{d[N_2O_5]}{dt} \] (The negative sign indicates that the concentration of \( N_2O_5 \) is decreasing.) - The rate of formation of \( O_2 \) is given by: \[ \text{Rate of formation of } O_2 = \frac{1}{1} \frac{d[O_2]}{dt} \] ### Step 2: Relate the Rates From the stoichiometry of the reaction, we can relate the rates of decomposition and formation. The coefficients in the balanced equation indicate how the rates are related: \[ - \frac{1}{2} \frac{d[N_2O_5]}{dt} = \frac{1}{1} \frac{d[O_2]}{dt} \] ### Step 3: Set Up the Ratio We need to find the ratio of the rate of decomposition of \( N_2O_5 \) to the rate of formation of \( O_2 \): \[ \text{Ratio} = \frac{-\frac{1}{2} \frac{d[N_2O_5]}{dt}}{\frac{d[O_2]}{dt}} \] ### Step 4: Substitute the Rate Relationships Using the relationship from Step 2, we can substitute: \[ \text{Ratio} = \frac{-\frac{1}{2} \frac{d[N_2O_5]}{dt}}{\frac{1}{2} \frac{d[N_2O_5]}{dt}} = \frac{2}{1} \] ### Step 5: Final Result Thus, the ratio of the rate of decomposition of \( N_2O_5 \) to the rate of formation of \( O_2 \) is: \[ \text{Ratio} = 2:1 \]
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