Home
Class 12
CHEMISTRY
The colour change of an indicator Hln in...

The colour change of an indicator Hln in acid base titrations is given below
`underset("Colour x")(Hln(aq))hArr H+(aq)+ln^(-)underset("Colour Y")((aq))`
Which of the following statements is correct?

A

In a strong alkaline solution colour Y will be observed

B

In a strong acidic solution colour Y will be observed

C

Concentration of `ln^(-)` is higher than that of Hln at the equivalence point

D

In a strong alkaline solution colour X is observed

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the color change of the indicator HIn in acid-base titrations, we will analyze the dissociation reaction and the implications of different pH environments on the indicator's color. ### Step-by-Step Solution: 1. **Understanding the Indicator Reaction**: The indicator HIn in aqueous solution can be represented as: \[ \text{HIn (aq)} \rightleftharpoons \text{H}^+ (aq) + \text{In}^- (aq) \] - Here, HIn has color X, and when it dissociates, it produces H⁺ ions and In⁻ ions, which have color Y. 2. **Analyzing the Color Changes**: - In acidic solutions (high concentration of H⁺), the equilibrium will shift to the left, favoring the formation of HIn, resulting in color X being observed. - In alkaline solutions (low concentration of H⁺), the equilibrium will shift to the right, favoring the formation of In⁻, resulting in color Y being observed. 3. **Evaluating the Statements**: - **Statement 1**: In a strong alkaline solution, color Y will be observed. - **True**: In strong alkaline conditions, the concentration of H⁺ ions is low, shifting the equilibrium to the right, thus color Y is observed. - **Statement 2**: In a strong acidic solution, color Y will be observed. - **False**: In strong acidic conditions, the concentration of H⁺ ions is high, shifting the equilibrium to the left, thus color X is observed. - **Statement 3**: Concentration of In⁻ is higher than that of HIn at the equivalence point. - **False**: At the equivalence point in a titration, the amounts of acid and base are equal, and the concentration of HIn and In⁻ will depend on the specific conditions of the titration. - **Statement 4**: In a strong alkaline solution, color X is observed. - **False**: As established, in strong alkaline conditions, color Y is observed. 4. **Conclusion**: The only correct statement is that in a strong alkaline solution, color Y will be observed. ### Final Answer: The correct statement is: **In a strong alkaline solution, color Y will be observed.**
Promotional Banner

Similar Questions

Explore conceptually related problems

In acidic medium which of the following does not change its colour:

Which of the following colour changes shown during redox titrations is not correct ?

Bromine water is brown and weakly acidic due to following equilibrium : underset( " Brown " ) (Br_2(aq) ) + 2H_2O hArr underset( " Colourless ")( HBrO(aq))+ H_3O^(+) (l) + underset( " Colourless ") (Br^(-)(aq)) When sodium hydroxide is added to the solution , the solution becomes colourless but the colour return when hydrochloric acid is added. Explain this observation.

Which of the following statements about a weak acid strong base titration is//are correct?

K_(4)[Fe(CN)_(6)]+M^(x+)(aq.)to underset("Coloured precipitate")(M_(4)[Fe(CN)_(6)]_(x)darr) Which of the following cation does not respond to the above reaction?

K_(4)[Fe(CN)_(6)]+M^(x+)(aq.)to underset("Coloured precipitate")(M_(4)[Fe(CN)_(6)]_(x)darr) Which of the following cation does not respond to the above reaction?

Mention the colour changes observed when the following indicators are added to acids : Methyl orange solution

Colour of CrO_(4)^(2-) (aq.) is not changed by

Acid-base indicators are either weak organic acids or weak organic bases. Indicator change colour in dilute solution when the hydonium ion concentration reaches a particular colour For example. Phenolphthalein is a coloureless substance in any aqueous solution with a pH less than 8.3 In between the pH range 8.3 to 10, transition of colour (colourless to pink ) takes place and if pH of solution is greater than 10 solution is dark pink. Considering an acid indicator Hln, the equilibrium involving it and its conjgate base In^(-) can be represented as : " " underset("acidic from")(HIn)hArrH^(+)underset("basic from")(In^(-)) pH of solution can be computed as : " " pH=pK_(In)+log.([IN^(-)])/([HIn]) In general, transition of colour takes place in between the pH range pK_(In+-1 Which of the following indicator is most suitable for titration of HB with strong base :

Acid-base indicators are either weak organic acids or weak organic bases. Indicator change colour in dilute solution when the hydonium ion concentration reaches a particular calur For example. Phenolphthalein is a coloureless stbstance in any aqueous solution with a pH less than 8.3 In between the pH range 8.3 to 10, transition of colour (colourless to pink ) takes place and if pH of solution is greater than 10 solution is dark pink. Considering an acid indicator Hln, the equilibrium involving it and its conjgate base In^(-) can be represented as : " " underset("acidic from")(HIn)hArrH^(+)underset("basic from")(In^(-)) pH of solution can be computed as : " " pH=pK_(In)+log.([IN^(-)])/([HIn]) In general, transition of colour takes place in between the pH range pK_(In+-1. An indicator is a weak acid and pH range is 4.0 to 6.0. If indicator in 50% ionized in a given solution then what is the inization constant of the acid ?