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100 mL of 0.3 M acetic acid is shaken wi...

100 mL of 0.3 M acetic acid is shaken with 0.8 g wood charcoal. The final concentration of acetic acid in the solution after adsorption is 0.125 M. The mass of acetic acid adsorbed per gram of charcoal is :

A

1.05 g

B

0.0131 g

C

1.31 g

D

0.131 g

Text Solution

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To solve the problem step by step, we will follow the outlined process in the video transcript while ensuring clarity and precision. ### Step 1: Calculate Initial Moles of Acetic Acid Given: - Volume of acetic acid solution (V1) = 100 mL = 0.1 L - Molarity of acetic acid (C1) = 0.3 M Using the formula: \[ \text{Moles} = \text{Volume (L)} \times \text{Molarity (M)} \] \[ \text{Initial moles of acetic acid} = 0.1 \, \text{L} \times 0.3 \, \text{mol/L} = 0.03 \, \text{mol} = 30 \, \text{mmol} \] ### Step 2: Calculate Final Moles of Acetic Acid Given: - Final concentration of acetic acid (C2) = 0.125 M Using the same formula: \[ \text{Final moles of acetic acid} = 0.1 \, \text{L} \times 0.125 \, \text{mol/L} = 0.0125 \, \text{mol} = 12.5 \, \text{mmol} \] ### Step 3: Calculate Moles of Acetic Acid Adsorbed Now, we can find the moles of acetic acid that were adsorbed by subtracting the final moles from the initial moles: \[ \text{Moles adsorbed} = \text{Initial moles} - \text{Final moles} \] \[ \text{Moles adsorbed} = 30 \, \text{mmol} - 12.5 \, \text{mmol} = 17.5 \, \text{mmol} \] ### Step 4: Calculate the Mass of Acetic Acid Adsorbed Next, we need to find the mass of acetic acid adsorbed. First, we calculate the molecular weight of acetic acid (CH3COOH): - Carbon (C) = 12 g/mol × 2 = 24 g/mol - Hydrogen (H) = 1 g/mol × 4 = 4 g/mol - Oxygen (O) = 16 g/mol × 2 = 32 g/mol Thus, the molecular weight of acetic acid is: \[ \text{Molecular weight} = 24 + 4 + 32 = 60 \, \text{g/mol} \] Now, we can calculate the mass of acetic acid adsorbed: \[ \text{Mass} = \text{Moles} \times \text{Molecular Weight} \] \[ \text{Mass adsorbed} = 17.5 \, \text{mmol} \times 60 \, \text{g/mol} = 1.05 \, \text{g} = 1050 \, \text{mg} \] ### Step 5: Calculate Mass of Acetic Acid Adsorbed per Gram of Charcoal Given that the mass of charcoal used is 0.8 g, we can find the mass of acetic acid adsorbed per gram of charcoal: \[ \text{Mass per gram of charcoal} = \frac{\text{Mass adsorbed}}{\text{Mass of charcoal}} = \frac{1050 \, \text{mg}}{0.8 \, \text{g}} = 1312.5 \, \text{mg/g} \] Converting mg to g: \[ \text{Mass per gram of charcoal} = \frac{1312.5 \, \text{mg}}{1000} = 1.3125 \, \text{g} \] ### Final Answer The mass of acetic acid adsorbed per gram of charcoal is approximately **1.31 g**. ---
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