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The atomic masses of He and Ne are 4 an...

The atomic masses of He and Ne are 4 and 20 amu respectively . The value of the de Broglie wavelength of He gas at`-73.^(@)C` is ''M'' times that of the de Broglie wavelength of Ne at `727.^(@)C.` M is

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To solve the problem, we need to determine the value of \( M \) which represents the ratio of the de Broglie wavelengths of helium (He) gas at \(-73^\circ C\) and neon (Ne) gas at \(727^\circ C\). ### Step-by-step Solution: 1. **Convert Temperatures to Kelvin:** - For Helium at \(-73^\circ C\): \[ T_{He} = 273 - 73 = 200 \, K \] - For Neon at \(727^\circ C\): \[ T_{Ne} = 727 + 273 = 1000 \, K \] 2. **Write the Formula for de Broglie Wavelength:** The de Broglie wavelength (\( \lambda \)) is given by the formula: \[ \lambda = \frac{h}{\sqrt{3 m k T}} \] where: - \( h \) = Planck's constant - \( m \) = mass of the gas particle - \( k \) = Boltzmann's constant - \( T \) = temperature in Kelvin 3. **Calculate the de Broglie Wavelength for He:** Using the formula for He: \[ \lambda_{He} = \frac{h}{\sqrt{3 \cdot m_{He} \cdot k \cdot T_{He}}} \] where \( m_{He} = 4 \, \text{amu} \) and \( T_{He} = 200 \, K \). 4. **Calculate the de Broglie Wavelength for Ne:** Using the formula for Ne: \[ \lambda_{Ne} = \frac{h}{\sqrt{3 \cdot m_{Ne} \cdot k \cdot T_{Ne}}} \] where \( m_{Ne} = 20 \, \text{amu} \) and \( T_{Ne} = 1000 \, K \). 5. **Set Up the Ratio of Wavelengths:** According to the problem, we have: \[ \lambda_{He} = M \cdot \lambda_{Ne} \] Substituting the expressions for the wavelengths: \[ \frac{h}{\sqrt{3 \cdot 4 \cdot k \cdot 200}} = M \cdot \frac{h}{\sqrt{3 \cdot 20 \cdot k \cdot 1000}} \] 6. **Cancel Out Common Terms:** Since \( h \) and \( \sqrt{3} \) and \( k \) are common in both sides, we can simplify: \[ \frac{1}{\sqrt{4 \cdot 200}} = M \cdot \frac{1}{\sqrt{20 \cdot 1000}} \] 7. **Cross Multiply:** \[ \sqrt{20 \cdot 1000} = M \cdot \sqrt{4 \cdot 200} \] 8. **Square Both Sides:** \[ 20 \cdot 1000 = M^2 \cdot (4 \cdot 200) \] 9. **Calculate the Values:** - Left side: \[ 20 \cdot 1000 = 20000 \] - Right side: \[ 4 \cdot 200 = 800 \] Thus, we have: \[ 20000 = M^2 \cdot 800 \] 10. **Solve for \( M^2 \):** \[ M^2 = \frac{20000}{800} = 25 \] 11. **Find \( M \):** \[ M = \sqrt{25} = 5 \] ### Final Answer: \[ M = 5 \]
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