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C(4)H(7)OCl overset(NH(3))rarr C(4)H(9)O...

`C_(4)H_(7)OCl overset(NH_(3))rarr C_(4)H_(9)ON underset(KOH)overset(Br_(2))rarr CH_(3)CH_(2)CH_(2)NH_(2)` Compound (X) is

A

B

C

D

Text Solution

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The correct Answer is:
To determine the initial compound (X) in the reaction sequence given, we can break down the process step by step. ### Step 1: Identify the Final Product The final product given is CH₃CH₂CH₂NH₂, which is a primary amine. This suggests that the compound before the final step was likely an amide, as the reaction involves the Hofmann bromamide reaction. ### Step 2: Determine the Amide Structure The Hofmann bromamide reaction converts an amide to a primary amine. Therefore, we can deduce that the compound before the addition of Br₂ and KOH was an amide. The structure of the amine CH₃CH₂CH₂NH₂ indicates that the corresponding amide would be CH₃CH₂CH₂C(O)NH₂. ### Step 3: Identify the Preceding Compound The compound that reacts with NH₃ to form the amide must be an acyl chloride (since acyl chlorides react with ammonia to form amides). The acyl chloride corresponding to the amide CH₃CH₂CH₂C(O)NH₂ would be CH₃CH₂CH₂C(O)Cl. ### Step 4: Write the Structure of Compound (X) Thus, the initial compound (X) must be CH₃CH₂CH₂C(O)Cl, which can be represented as C₄H₇OCl. This matches the molecular formula given in the question. ### Conclusion Therefore, the initial compound (X) is **butanoyl chloride (C₄H₇OCl)**. ### Summary of Steps: 1. Identify the final product as a primary amine. 2. Determine that the compound before the final step was an amide. 3. Identify the acyl chloride that reacts with NH₃ to form the amide. 4. Conclude that the initial compound (X) is butanoyl chloride.
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