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If Deltar(1) represents the difference i...

If `Deltar_(1)` represents the difference in radii of statonary orbitals for n = 3 and n = 4 in a hydrogen atom and `Deltar_(2)` represents the difference in radii of stationary orbits for n = 8 and n = 9, then the value of `(Deltar_(1))/(Deltar_(2))` is

A

0.71

B

0.41

C

2.43

D

14.82

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will use Bohr's model of the hydrogen atom, which gives us the radius of stationary orbits. The formula for the radius of the nth orbit in a hydrogen atom is given by: \[ r_n = a_0 n^2 \] where \( a_0 \) is the Bohr radius and \( n \) is the principal quantum number. ### Step 1: Calculate \( \Delta r_1 \) for \( n = 3 \) and \( n = 4 \) 1. **Calculate \( r_3 \)**: \[ r_3 = a_0 \cdot 3^2 = a_0 \cdot 9 \] 2. **Calculate \( r_4 \)**: \[ r_4 = a_0 \cdot 4^2 = a_0 \cdot 16 \] 3. **Calculate \( \Delta r_1 \)**: \[ \Delta r_1 = r_4 - r_3 = (16 a_0 - 9 a_0) = 7 a_0 \] ### Step 2: Calculate \( \Delta r_2 \) for \( n = 8 \) and \( n = 9 \) 1. **Calculate \( r_8 \)**: \[ r_8 = a_0 \cdot 8^2 = a_0 \cdot 64 \] 2. **Calculate \( r_9 \)**: \[ r_9 = a_0 \cdot 9^2 = a_0 \cdot 81 \] 3. **Calculate \( \Delta r_2 \)**: \[ \Delta r_2 = r_9 - r_8 = (81 a_0 - 64 a_0) = 17 a_0 \] ### Step 3: Calculate \( \frac{\Delta r_1}{\Delta r_2} \) Now, we can find the ratio of the differences in radii: \[ \frac{\Delta r_1}{\Delta r_2} = \frac{7 a_0}{17 a_0} = \frac{7}{17} \] ### Step 4: Approximate the value Calculating the decimal value: \[ \frac{7}{17} \approx 0.4118 \approx 0.41 \] Thus, the final answer is: \[ \frac{\Delta r_1}{\Delta r_2} \approx 0.41 \] ### Final Answer: The value of \( \frac{\Delta r_1}{\Delta r_2} \) is approximately \( 0.41 \). ---
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