Home
Class 12
CHEMISTRY
Two moles of an ideal monoatomic gas at ...

Two moles of an ideal monoatomic gas at 5 bar and 300 K are expanded irreversibly up to a final pressure of 1 bar and 240 K against an external pressure of 0.5 bar. The work done by the gas is `-xR`. The value of x' is
(Here 'R' is gas constant)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to calculate the work done by the gas during its irreversible expansion. Let's break down the steps: ### Step 1: Calculate Initial Volume (V1) Using the ideal gas equation \( PV = nRT \): 1. Given: - Number of moles \( n = 2 \) - Initial pressure \( P_1 = 5 \) bar - Initial temperature \( T_1 = 300 \) K - Gas constant \( R \) (we will keep it as \( R \)) 2. Rearranging the equation: \[ V_1 = \frac{nRT_1}{P_1} \] 3. Substituting the values: \[ V_1 = \frac{2 \times R \times 300}{5} \] \[ V_1 = \frac{600R}{5} = 120R \] ### Step 2: Calculate Final Volume (V2) Using the same ideal gas equation for the final state: 1. Given: - Final pressure \( P_2 = 1 \) bar - Final temperature \( T_2 = 240 \) K 2. Rearranging the equation: \[ V_2 = \frac{nRT_2}{P_2} \] 3. Substituting the values: \[ V_2 = \frac{2 \times R \times 240}{1} \] \[ V_2 = 480R \] ### Step 3: Calculate Change in Volume (ΔV) Now we find the change in volume: \[ \Delta V = V_1 - V_2 \] Substituting the values: \[ \Delta V = 120R - 480R = -360R \] ### Step 4: Calculate Work Done (W) The work done by the gas during irreversible expansion against an external pressure is given by: \[ W = P_{\text{external}} \times \Delta V \] 1. Given: - External pressure \( P_{\text{external}} = 0.5 \) bar 2. Substituting the values: \[ W = 0.5 \times (-360R) \] \[ W = -180R \] ### Step 5: Relate Work Done to the Given Expression According to the problem, the work done by the gas is given as \( -xR \). We have calculated: \[ W = -180R \] Thus, we can equate: \[ -xR = -180R \] ### Step 6: Solve for x From the equation above, we find: \[ x = 180 \] ### Final Answer The value of \( x \) is \( 180 \). ---
Promotional Banner

Similar Questions

Explore conceptually related problems

A gas expands from 4.0 L to 4.5 L against a constant external pressure of 1 atm. The work done by the gas is (1 L-atm = 101.3 J)

Two moles of a gas at 8.21 bar and 300 K are expanded at constant temperature up to 2.73 bar against a constant pressure of 1 bar. How much work (in Latm) is done by the gas? (neglect the sign)

5 mole of an ideal gas expand isothermally and irreversibly from a pressure of 10 atm to 1 atm against a constant external pressure of 2 atm. w_(irr) at 300 K is :

A gas expands from 10 litres to 20 litres against a constant external pressure of 10 atm. The pressure-volume work done by the system is

One mole of an ideal gas (C_(v,m)=(5)/(2)R) at 300 K and 5 atm is expanded adiabatically to a final pressure of 2 atm against a constant pressure of 2 atm. Final temperature of the gas is :

Under isothermal condition, a gas at 300 K expands from 0.1 L to 0.25 L against a constant external pressure of 2 bar. The work done by the gas is (Given that 1 L bar = 100 J)

An ideal gas is allowed to expand from 1L to 10 L against a constant external pressure of 1 bar. The work done in x xx 10^(y)J . The numerical value of x is_____.

Two moles of an ideal monoatomic gas occupy a volume 2V at temperature 300K, it expands to a volume 4V adiabatically, then the final temperature of gas is

An ideal gas at 300K is expanded isothermally to double its volume,then pressure of the gas will be

One mole of an ideal monoatomic gas at temperature T and volume 1L expands to 2L against a constant external pressure of one atm under adiabatic conditions, then final temperature of gas will be: