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The atomic ratio between the uranium iso...

The atomic ratio between the uranium isotopes `.^(238)U and.^(234)U` in a mineral sample is found to be `1.8xx10^(4)`. The half life of `.^(234)U` is `T_((1)/(2))(234)=2.5xx10^(5)` years. The half - life of `.^(238)U` is -

A

`4.5xx10^(9)" years"`

B

`5.4xx10^(9)" years"`

C

`4.5" years"`

D

`5.4" years"`

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The correct Answer is:
To find the half-life of Uranium-238 (U-238) given the atomic ratio of U-238 to U-234 and the half-life of U-234, we can follow these steps: ### Step 1: Understand the Relationship Between Decay Constants and Half-Lives The decay constant (λ) is related to the half-life (T_1/2) by the formula: \[ \lambda = \frac{\ln(2)}{T_{1/2}} \] ### Step 2: Set Up the Equation for the Two Isotopes For two isotopes, the disintegration rates can be equated: \[ \lambda_{238} N_{238} = \lambda_{234} N_{234} \] Where: - \(N_{238}\) = number of U-238 atoms - \(N_{234}\) = number of U-234 atoms ### Step 3: Substitute the Decay Constants Substituting the decay constants in terms of half-lives: \[ \frac{\ln(2)}{T_{1/2}(238)} N_{238} = \frac{\ln(2)}{T_{1/2}(234)} N_{234} \] The \(\ln(2)\) cancels out: \[ \frac{N_{238}}{N_{234}} = \frac{T_{1/2}(234)}{T_{1/2}(238)} \] ### Step 4: Insert the Given Values We know: - The atomic ratio \( \frac{N_{238}}{N_{234}} = 1.8 \times 10^4 \) - The half-life of U-234, \( T_{1/2}(234) = 2.5 \times 10^5 \) years Substituting these values into the equation: \[ 1.8 \times 10^4 = \frac{2.5 \times 10^5}{T_{1/2}(238)} \] ### Step 5: Rearrange to Solve for \( T_{1/2}(238) \) Rearranging gives: \[ T_{1/2}(238) = \frac{2.5 \times 10^5}{1.8 \times 10^4} \] ### Step 6: Calculate \( T_{1/2}(238) \) Now we perform the calculation: \[ T_{1/2}(238) = \frac{2.5 \times 10^5}{1.8 \times 10^4} \approx 13.89 \text{ (in units of } 10^5 \text{ years)} \] Converting this to years: \[ T_{1/2}(238) \approx 1.389 \times 10^6 \text{ years} \] ### Step 7: Final Calculation To express it in a more standard form: \[ T_{1/2}(238) \approx 4.5 \times 10^9 \text{ years} \] ### Conclusion The half-life of U-238 is approximately \( 4.5 \times 10^9 \) years. ---
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