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The characteristics X-rays wavelength is...

The characteristics X-rays wavelength is related to atomic number by the relation `sqrt(nu)=a(Z-b)`
When Z is the atomic number, a and b are Mosley's constants. If `lambda_(1)=2.886Å` and `lambda_(2)=2.365Å` corresponding to `Z_(1)=55 and Z_(2)=60` respectively, the value of Z corresponding to `lambda=2.660Å` is

A

55

B

57

C

74

D

507

Text Solution

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The correct Answer is:
To solve the problem, we will follow the steps outlined in the video transcript and derive the value of the atomic number \( Z \) corresponding to the wavelength \( \lambda = 2.660 \, \text{Å} \). ### Step 1: Understand the relationship The relationship given is: \[ \sqrt{\nu} = a(Z - b) \] where \( \nu \) is the frequency, \( Z \) is the atomic number, and \( a \) and \( b \) are Mosley's constants. The frequency \( \nu \) can be expressed in terms of wavelength \( \lambda \) as: \[ \nu = \frac{c}{\lambda} \] where \( c \) is the speed of light. ### Step 2: Set up equations for the given data For the first case with \( \lambda_1 = 2.886 \, \text{Å} \) and \( Z_1 = 55 \): \[ \sqrt{\frac{c}{2.886}} = a(55 - b) \quad \text{(Equation 1)} \] For the second case with \( \lambda_2 = 2.365 \, \text{Å} \) and \( Z_2 = 60 \): \[ \sqrt{\frac{c}{2.365}} = a(60 - b) \quad \text{(Equation 2)} \] ### Step 3: Divide the two equations Dividing Equation 1 by Equation 2 gives: \[ \frac{\sqrt{\frac{c}{2.365}}}{\sqrt{\frac{c}{2.886}}} = \frac{a(55 - b)}{a(60 - b)} \] This simplifies to: \[ \sqrt{\frac{2.886}{2.365}} = \frac{55 - b}{60 - b} \] ### Step 4: Calculate the left side Calculating the left side: \[ \sqrt{\frac{2.886}{2.365}} \approx 0.905 \] Thus, we have: \[ 0.905 = \frac{55 - b}{60 - b} \] ### Step 5: Cross-multiply and solve for \( b \) Cross-multiplying gives: \[ 0.905(60 - b) = 55 - b \] Expanding and rearranging: \[ 54.3 - 0.905b = 55 - b \] \[ b - 0.905b = 55 - 54.3 \] \[ 0.095b = 0.7 \] \[ b = \frac{0.7}{0.095} \approx 7.36 \] ### Step 6: Substitute \( b \) back into Equation 1 Now substituting \( b \) back into Equation 1: \[ \sqrt{\frac{c}{2.886}} = a(55 - 7.36) \] This simplifies to: \[ \sqrt{\frac{c}{2.886}} = a(47.64) \] ### Step 7: Calculate \( a \) Using \( c = 3 \times 10^8 \, \text{m/s} \): \[ \sqrt{\frac{3 \times 10^8}{2.886 \times 10^{-10}}} = a(47.64) \] Calculating the left side: \[ \sqrt{1.041 \times 10^{18}} \approx 1.01 \times 10^9 \] Thus: \[ 1.01 \times 10^9 = a(47.64) \] Solving for \( a \): \[ a = \frac{1.01 \times 10^9}{47.64} \approx 2.12 \times 10^7 \] ### Step 8: Find \( Z \) for \( \lambda = 2.660 \, \text{Å} \) Now we need to find \( Z \) for \( \lambda = 2.660 \, \text{Å} \): \[ \sqrt{\frac{c}{2.660}} = a(Z - b) \] Substituting known values: \[ \sqrt{\frac{3 \times 10^8}{2.660 \times 10^{-10}}} = 2.12 \times 10^7(Z - 7.36) \] Calculating the left side: \[ \sqrt{1.13 \times 10^{18}} \approx 1.06 \times 10^9 \] Thus: \[ 1.06 \times 10^9 = 2.12 \times 10^7(Z - 7.36) \] Solving for \( Z \): \[ Z - 7.36 = \frac{1.06 \times 10^9}{2.12 \times 10^7} \approx 50.04 \] \[ Z \approx 57.40 \] Rounding to the nearest whole number gives: \[ Z \approx 57 \] ### Final Answer The value of \( Z \) corresponding to \( \lambda = 2.660 \, \text{Å} \) is approximately **57**.
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