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The capacity of a vessel is 3 L. It cont...

The capacity of a vessel is `3 L`. It contains `6 g` oxygen, `8 g` nitrogen and `5 g CO_(2)` mixture at `27^(@)C`, If `R = 8.31 J//mol K`, then the pressure in the vessel in `N//m^(2)` will be (approx.)

A

`5xx10^(5)`

B

`5xx10^(4)`

C

`1xx10^(6)`

D

`1xx10^(5)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the pressure in the vessel containing a mixture of gases, we can use the ideal gas law equation: \[ PV = nRT \] Where: - \( P \) = pressure (in N/m²) - \( V \) = volume (in m³) - \( n \) = total number of moles of gas - \( R \) = universal gas constant (8.31 J/(mol·K)) - \( T \) = absolute temperature (in Kelvin) ### Step 1: Convert the volume from liters to cubic meters The volume of the vessel is given as 3 liters. To convert this to cubic meters: \[ V = 3 \, \text{L} = 3 \times 10^{-3} \, \text{m}^3 \] ### Step 2: Calculate the number of moles of each gas We will calculate the number of moles for each gas using the formula: \[ n = \frac{\text{mass}}{\text{molar mass}} \] 1. **For Oxygen (O₂)**: - Mass = 6 g - Molar mass = 32 g/mol \[ n_{O_2} = \frac{6 \, \text{g}}{32 \, \text{g/mol}} = \frac{6}{32} = 0.1875 \, \text{mol} \] 2. **For Nitrogen (N₂)**: - Mass = 8 g - Molar mass = 28 g/mol \[ n_{N_2} = \frac{8 \, \text{g}}{28 \, \text{g/mol}} = \frac{8}{28} = 0.2857 \, \text{mol} \] 3. **For Carbon Dioxide (CO₂)**: - Mass = 5 g - Molar mass = 44 g/mol \[ n_{CO_2} = \frac{5 \, \text{g}}{44 \, \text{g/mol}} = \frac{5}{44} = 0.1136 \, \text{mol} \] ### Step 3: Calculate the total number of moles Now, we can find the total number of moles \( n \): \[ n = n_{O_2} + n_{N_2} + n_{CO_2} \] \[ n = 0.1875 + 0.2857 + 0.1136 = 0.5868 \, \text{mol} \] ### Step 4: Convert the temperature to Kelvin The temperature is given as 27°C. To convert this to Kelvin: \[ T = 27 + 273 = 300 \, \text{K} \] ### Step 5: Substitute values into the ideal gas law equation Now we can substitute the values into the ideal gas law to find the pressure \( P \): \[ P = \frac{nRT}{V} \] Substituting the known values: \[ P = \frac{(0.5868 \, \text{mol}) \times (8.31 \, \text{J/(mol \cdot K)}) \times (300 \, \text{K})}{3 \times 10^{-3} \, \text{m}^3} \] Calculating the numerator: \[ P = \frac{(0.5868) \times (8.31) \times (300)}{3 \times 10^{-3}} \] \[ = \frac{1458.036}{3 \times 10^{-3}} = 486012 \, \text{N/m}^2 \] ### Step 6: Approximate the pressure The calculated pressure is approximately: \[ P \approx 4.86 \times 10^5 \, \text{N/m}^2 \] ### Final Answer Thus, the pressure in the vessel is approximately \( 5 \times 10^5 \, \text{N/m}^2 \). ---
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