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The intermediate product (X) formed in t...

The intermediate product (X) formed in the following reaction is
`B_(2)H_(6)+6NH_(3)rarr 3K overset("heat")rarr 2B_(3)N_(3)H_(6)+12H_(2)`

A

`[BH(NH_(3))_(3)]^(+)[BH_(4)]^(-)`

B

`[BH_(2)(NH_(3))_(4)]^(+)[BH_(4)]^(-)`

C

`[BH(NH_(3))_(4)]^(+)[BH_(4)]^(-)`

D

`[BH_(2)(NH_(3))_(2)]^(+)[BH_(4)]^(-)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the intermediate product (X) formed in the reaction of \( B_2H_6 \) with \( NH_3 \), we can break down the process step by step. ### Step 1: Understand the Reaction The reaction given is: \[ B_2H_6 + 6NH_3 \rightarrow 3K \] where \( K \) is the intermediate product that will further react upon heating to yield: \[ 3K \xrightarrow{\text{heat}} 2B_3N_3H_6 + 12H_2 \] ### Step 2: Identify the Reactants - **Boron Hydride**: \( B_2H_6 \) (Diborane) - **Ammonia**: \( NH_3 \) ### Step 3: Analyze the Formation of the Intermediate When \( B_2H_6 \) reacts with \( NH_3 \), the expected intermediate product \( K \) is formed. The reaction involves the coordination of ammonia with boron hydride. ### Step 4: Write the Reaction for the Intermediate Formation The reaction can be represented as: \[ B_2H_6 + 6NH_3 \rightarrow 2(BH_2 \cdot NH_3) + 2BH_4^- \] This indicates that the intermediate \( K \) can be represented as a complex of boron and ammonia. ### Step 5: Identify the Structure of the Intermediate The intermediate \( K \) can be represented as: \[ K = (BH_2 \cdot NH_3)_2 + BH_4^- \] This structure indicates that the intermediate consists of boron-nitrogen bonds and is a complex of boron hydride and ammonia. ### Step 6: Finalize the Intermediate Product The final intermediate product \( K \) can be identified as: \[ K = (BH_2 \cdot NH_3)_2 \] This is also known as a boron-nitrogen complex. ### Conclusion The intermediate product \( K \) formed in the reaction is: \[ K = (BH_2 \cdot NH_3)_2 + BH_4^- \]
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