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A list of species having the formula of `XZ_(4)` is given below `XeF_(4), SF_(4), SiF_(4), BF_(4)^(-), BrF_(4)^(-), [Cu(NH_(3))4]^(2+),[FeCl_(4)]^(2-), [CoCl_(4)]^(2-)` and `[PtCl_(4)]^(2-)`
Defining shape on the basis of the location of `X` and `Z` atoms, the total number of species having a square planar shape is

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To determine the total number of species having a square planar shape from the given list of compounds with the formula `XZ₄`, we will analyze each species one by one based on their hybridization and molecular geometry. ### Step-by-Step Solution: 1. **Identify the Species**: The given species are: - XeF₄ - SF₄ - SiF₄ - BF₄⁻ - BrF₄⁻ - [Cu(NH₃)₄]²⁺ - [FeCl₄]²⁻ - [CoCl₄]²⁻ - [PtCl₄]²⁻ 2. **Analyze Each Species**: - **XeF₄**: - Valence electrons: 8 (Xe) + 4 (F) = 12 - Hybridization: \( \frac{12}{2} = 6 \) → sp³d² - Shape: Square planar (4 F atoms in equatorial positions, 2 lone pairs in axial positions). - **SF₄**: - Valence electrons: 6 (S) + 4 (F) = 10 - Hybridization: \( \frac{10}{2} = 5 \) → sp³d - Shape: Seesaw (not square planar). - **SiF₄**: - Valence electrons: 4 (Si) + 4 (F) = 8 - Hybridization: \( \frac{8}{2} = 4 \) → sp³ - Shape: Tetrahedral (not square planar). - **BF₄⁻**: - Valence electrons: 3 (B) + 4 (F) + 1 (charge) = 8 - Hybridization: \( \frac{8}{2} = 4 \) → sp³ - Shape: Tetrahedral (not square planar). - **BrF₄⁻**: - Valence electrons: 7 (Br) + 4 (F) + 1 (charge) = 12 - Hybridization: \( \frac{12}{2} = 6 \) → sp³d² - Shape: Square planar (4 F atoms in equatorial positions, 2 lone pairs in axial positions). - **[Cu(NH₃)₄]²⁺**: - Oxidation state of Cu: +2 → 4s² 3d⁹ - Hybridization: dsp² (due to strong field ligands). - Shape: Square planar. - **[FeCl₄]²⁻**: - Oxidation state of Fe: +2 → 4s² 3d⁶ - Hybridization: sp³ (due to weak field ligands). - Shape: Tetrahedral (not square planar). - **[CoCl₄]²⁻**: - Oxidation state of Co: +2 → 4s² 3d⁷ - Hybridization: sp³ (due to weak field ligands). - Shape: Tetrahedral (not square planar). - **[PtCl₄]²⁻**: - Oxidation state of Pt: +2 → 6s² 5d⁸ - Hybridization: dsp² (due to strong field ligands). - Shape: Square planar. 3. **Count Square Planar Species**: - From the analysis, the species that exhibit a square planar shape are: - XeF₄ - BrF₄⁻ - [Cu(NH₃)₄]²⁺ - [PtCl₄]²⁻ Thus, the total number of species with a square planar shape is **4**. ### Final Answer: The total number of species having a square planar shape is **4**.
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