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The ratio of minimum wavelengths of Lyma...

The ratio of minimum wavelengths of Lyman and Balmer series will be

A

1.25

B

0.25

C

5

D

10

Text Solution

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The correct Answer is:
To find the ratio of the minimum wavelengths of the Lyman and Balmer series, we can follow these steps: ### Step 1: Understand the Concept of Minimum Wavelength The minimum wavelength corresponds to the transition of an electron from a higher energy level (n2) to the lowest energy level (n1). For the Lyman series, the electron transitions to n1 = 1, and for the Balmer series, it transitions to n1 = 2. ### Step 2: Use the Rydberg Formula The Rydberg formula for the wavelength (λ) of emitted light is given by: \[ \frac{1}{\lambda} = R_H \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where \( R_H \) is the Rydberg constant, \( n_1 \) is the lower energy level, and \( n_2 \) is the higher energy level. ### Step 3: Calculate Minimum Wavelength for Lyman Series For the Lyman series: - \( n_1 = 1 \) - \( n_2 = \infty \) Substituting these values into the Rydberg formula: \[ \frac{1}{\lambda_L} = R_H \left( \frac{1}{1^2} - \frac{1}{\infty^2} \right) = R_H \left( 1 - 0 \right) = R_H \] Thus, \[ \lambda_L = \frac{1}{R_H} \] ### Step 4: Calculate Minimum Wavelength for Balmer Series For the Balmer series: - \( n_1 = 2 \) - \( n_2 = \infty \) Substituting these values into the Rydberg formula: \[ \frac{1}{\lambda_B} = R_H \left( \frac{1}{2^2} - \frac{1}{\infty^2} \right) = R_H \left( \frac{1}{4} - 0 \right) = \frac{R_H}{4} \] Thus, \[ \lambda_B = \frac{4}{R_H} \] ### Step 5: Find the Ratio of Minimum Wavelengths Now, we need to find the ratio of the minimum wavelengths of the Lyman series to the Balmer series: \[ \frac{\lambda_L}{\lambda_B} = \frac{\frac{1}{R_H}}{\frac{4}{R_H}} = \frac{1}{4} \] ### Step 6: Convert to Decimal The ratio \(\frac{1}{4}\) can be expressed in decimal form: \[ \frac{1}{4} = 0.25 \] ### Conclusion The ratio of the minimum wavelengths of the Lyman and Balmer series is: \[ \text{Answer: } 0.25 \]
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