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Find the minimum attainable pressure of an ideal gas in the process `T = T_(0) + alpha V^(2)`, Where `T_(0)` and `alpha` are positive constant and `V` is the volume of one mole of gas. Draw the approximate `T -V` plot of this process.

A

`2Rsqrt(alphaT_(0))`

B

`3Rsqrt(alphaT_(0))`

C

3R

D

`3Rsqrt((alphaT_(0))/(2))`

Text Solution

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To find the minimum attainable pressure of an ideal gas in the process defined by the equation \( T = T_0 + \alpha V^2 \), where \( T_0 \) and \( \alpha \) are positive constants, we can follow these steps: ### Step 1: Relate Pressure, Volume, and Temperature For one mole of an ideal gas, the ideal gas law states: \[ PV = RT \] Where: - \( P \) is the pressure, - \( V \) is the volume, - \( R \) is the universal gas constant, - \( T \) is the temperature. ### Step 2: Substitute for Volume From the ideal gas law, we can express volume \( V \) in terms of pressure \( P \) and temperature \( T \): \[ V = \frac{RT}{P} \] ### Step 3: Substitute Volume into the Temperature Equation We substitute \( V \) into the given temperature equation: \[ T = T_0 + \alpha \left(\frac{RT}{P}\right)^2 \] This simplifies to: \[ T = T_0 + \alpha \frac{R^2 T^2}{P^2} \] ### Step 4: Rearranging the Equation Rearranging this equation gives: \[ P^2 = \frac{\alpha R^2 T^2}{T - T_0} \] ### Step 5: Express Pressure in Terms of Temperature Taking the square root of both sides, we find: \[ P = \sqrt{\frac{\alpha R^2 T^2}{T - T_0}} \] ### Step 6: Differentiate Pressure with Respect to Temperature To find the minimum pressure, we differentiate \( P \) with respect to \( T \) and set the derivative equal to zero: \[ \frac{dP}{dT} = \frac{1}{2} \left(\frac{\alpha R^2 T^2}{T - T_0}\right)^{-1/2} \cdot \left( \frac{d}{dT}\left(\frac{\alpha R^2 T^2}{T - T_0}\right) \right) = 0 \] ### Step 7: Solve the Derivative Using the quotient rule, we differentiate: \[ \frac{d}{dT}\left(\frac{\alpha R^2 T^2}{T - T_0}\right) = \frac{(T - T_0)(2\alpha R^2 T) - \alpha R^2 T^2}{(T - T_0)^2} \] Setting this derivative equal to zero gives: \[ (T - T_0)(2\alpha R^2 T) - \alpha R^2 T^2 = 0 \] This simplifies to: \[ 2T - T_0 = 0 \implies T = 2T_0 \] ### Step 8: Substitute Back to Find Minimum Pressure Now substituting \( T = 2T_0 \) back into the expression for \( P \): \[ P_{min} = \sqrt{\frac{\alpha R^2 (2T_0)^2}{2T_0 - T_0}} = \sqrt{4\alpha R^2 T_0} = 2R\sqrt{\alpha T_0} \] ### Conclusion Thus, the minimum attainable pressure of the ideal gas is: \[ P_{min} = 2R\sqrt{\alpha T_0} \]
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