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MeSiCl is used during polymerisation of ...

`MeSiCl` is used during polymerisation of organo silicones because

A

the chain length of organosilicon polymers can be controlled by adding `(CH_(3))_(3)SiCl`

B

`(CH_(3))_(3)SiCl` improves the quality and yield of the polymer

C

`(CH_(3))_(3)SiCl` does not block the end terminal of silicone polymer

D

`(CH_(3))_(3)SiCl` acts as a catalyst during polymerisation

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the use of `MeSiCl` during the polymerization of organosilicones, we can analyze the options provided and determine the correct reasoning based on the chemistry involved. ### Step-by-Step Solution: 1. **Understanding the Structure of `MeSiCl`:** - `MeSiCl` refers to a compound where a silicon atom (Si) is bonded to three methyl groups (Me) and one chlorine atom (Cl). This structure can be represented as `Si(CH3)3Cl`. 2. **Role of `MeSiCl` in Polymerization:** - During the polymerization of organosilicones, `MeSiCl` can react with silanol groups (Si-OH) present in the starting materials. The reaction typically involves the release of HCl and the formation of siloxane (Si-O-Si) linkages. 3. **Analyzing the Options:** - **Option 1:** "The chain length of organosilicone polymer can be controlled by adding `MeSiCl`." - This statement is **correct**. The presence of the methyl groups (CH3) prevents further polymerization by blocking the reactive sites, thus controlling the chain length. - **Option 2:** "CH3 whole thrice SiCl improves the quality and yield of the polymer." - This statement is **incorrect**. While `MeSiCl` can influence the properties of the polymer, it does not necessarily improve the yield or quality in a straightforward manner. - **Option 3:** "CH3 whole thrice SiCl does not block the end terminal of the carbon." - This statement is **incorrect**. The presence of the methyl groups does block further polymerization at the terminal ends, thus influencing the structure. - **Option 4:** "Act as a catalyst." - This statement is **incorrect**. `MeSiCl` does not act as a catalyst; instead, it participates in the polymerization process. 4. **Conclusion:** - The only correct statement is that the chain length of organosilicone polymer can be controlled by adding `MeSiCl`. This is because the methyl groups prevent further reactions, thus limiting the growth of the polymer chain. ### Final Answer: `MeSiCl` is used during polymerization of organo silicones because it controls the chain length of the organosilicone polymer by blocking further polymerization.
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